Original scientific paper

Chloride and Bromide Complexes of Lead(II) in Aqueous Melts of Calcium Dinitrate - Ammonium Nitrate

I. J. Zsigrai ; Institute of Chemistry, Faculty of Sciences, University of Novi Sad
M. R. Mićović ; Institute of Chemistry, Faculty of Sciences, University of Novi Sad
I. J. Gal ; Department of Chemistry, Faculty of Sciences, University of Belgrade

Abstract

The formation constants of PbCl+, PbCh, PbBr• and PbBr2 in
melts of Ca(N03)2 • a NH4N03 · x H20 (a = 1.5, 2.33; x = 3-9) at
323 and 338 K have been determined from E 1\lF measurements in
suitable concentration cells. The results are discussed in terms of
Braunstein's ionic association model based on quasi-lattice statistical
mechanics.

Keywords

Hrčak ID:

195849

URI

https://hrcak.srce.hr/195849

Publication date:

1.3.1980.

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