Original scientific paper

Visible Spectra of Some Monoacidopentaammine and Diacidotetraammine Complexes of Cobalt(III)

Suk-Yee Chan ; Department of Chemistry,. The Chinese University of Hong Kong Shatin, N. T. Hong Kong
Wai-Kee Li ; Department of Chemistry,. The Chinese University of Hong Kong Shatin, N. T. Hong Kong

Abstract

The spin-allowed transitions in the visible spectra of some
rr.onoacidopentaammine and diacidotetraammine complexes of
Co(III), with the acido groups being C03z--, H20, N02-, 02C3H5-,
p-, No3-, ci-, and Br-, have been resolved and the relevant crystal
field and Racah parameters determined with a modified version of
the model originally proposed by Wentworth and Piper. The tesults
appear to be consistent within the series and agree well with those
reported in the literature for structurally related systems.

Keywords

Hrčak ID:

195907

URI

https://hrcak.srce.hr/195907

Publication date:

19.4.1979.

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