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Original scientific paper

The Influence of Substituents on The Rate of the Intramolecular Diels-Alder Reaction of Allylaryl(2-furfuryl)amines

Ž. Klepo ; Laboratory of Organic Chemistry, Faculty of TechnoLogy, and Institute of Organic Chemistry and Biochemistry, University of Zagreb, 41000 Zagreb, Croatia, Yugoslavia
K. Jakopčić ; Laboratory of Organic Chemistry, Faculty of TechnoLogy, and Institute of Organic Chemistry and Biochemistry, University of Zagreb, 41000 Zagreb, Croatia, Yugoslavia


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Abstract

Some new examples of -intramolecular Diel-s-Alder reaction
of allylaryl(2-furfuryl)amines are given, and the influence of
substituents on the rate of the reaction is studied. Unlike para
substituents, ortho substitution of the N-aryl group or substitution
in position 5 of the furan nucleus decrease the rate of the [4 + 2]
cycloaddition.

Keywords

Hrčak ID:

196693

URI

https://hrcak.srce.hr/196693

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