Original scientific paper

Ferrocene Compounds. IV. Reactions of Ferrocene with Glutaryl Chloride

M. Laćan ; Laboratory of Organic Chemistry and Technology, Biochemistry Department, Faculty of Technology, University of Zagreb, 41000 Zagreb, Croatia, Yugoslavia
V. Rapić ; Laboratory of Organic Chemistry and Technology, Biochemistry Department, Faculty of Technology, University of Zagreb, 41000 Zagreb, Croatia, Yugoslavia

Abstract

The reactions of ferrocene with glutaryl chloride, in the
presence of aluminium chloride, were investigated. Depending
upon the reaction conditions and the molar ratios of reactants,
ll-ferrocenyl-11-oxovaleric acid (I), 1,5-diferrocenyl-1,5-pentanedione
(III) (the product of intermolecular acylation), and homoannularly
cyclized 1,2-(a,E-dioxopentamethylene)ferrocene (V) were
obtained. These reactions proceeded v;ia ll-ferrocenyl-11-oxovaleric
acid chloride (la).

Keywords

Hrčak ID:

196838

URI

https://hrcak.srce.hr/196838

Publication date:

20.7.1974.

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