Croatica Chemica Acta, Vol. 45 No. 3, 1973.
Original scientific paper
Heterocycles. CI. Syntheses and Isomerizations of Some Allylthio Nitrogen Heterocycles
M. Kočevar
; Department of Chemistry, University of L j ubljana, 61000 Ljubljana, Slovenia, Yugoslavia
B. Stanovnik
; Department of Chemistry, University of L j ubljana, 61000 Ljubljana, Slovenia, Yugoslavia
M. Tišler
; Department of Chemistry, University of L j ubljana, 61000 Ljubljana, Slovenia, Yugoslavia
Abstract
Allylthio nitrogen heterocycles were isomerized under the
influence of base into the corresponding propenylthio analogs. Subsequently,
isomerization of the resultant cis-propenylthio compounds
afforded the trans-isomers. In the case of 2-allylthiobenzothiazole
isomerization is followed by hydrolytic cleavage of the side chain.
Similar behaviour was observed in the 1,2,3-benzotriazine series.
Keywords
Hrčak ID:
197016
URI
Publication date:
12.11.1973.
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