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Croatica Chemica Acta, Vol. 45 No. 2, 1973.

Original scientific paper

Mass Spectra of Labeled Cyclopentanols

K. Humski ; Institute »Ruder Boskovic«, 41000 Zagreb
L. Klasinc ; Institute »Ruder Boskovic«, 41000 Zagreb
D. Kovačević ; Institute »Ruder Boskovic«, 41000 Zagreb

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Abstract

The fragmentation of cyclopentanol has been studied by employing
the deuterium labeling technique. Starting from the molecular
ion the following specific processes could be established:
loss of H from the position 1, loss of CH3 formed mainly from 2
(or 5) position after a-scission, loss of H 2 0 as a 1,3-elimination,
and loss of C2H 5 generated from 2 and 3 or 4 and 5 positions plus
one hydrogen from position 5 or 2, respectively. The results are
discussed.

Keywords

Hrčak ID:

197032

URI

https://hrcak.srce.hr/197032

Publication date:

30.6.1973.

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