Croatica Chemica Acta, Vol. 44 No. 2, 1972.
Original scientific paper
Mass Spectra of Bicyclo[2.2.1 ]-2-heptanols
K. Humski
; Institute »Ruder Boskovic«, 41000 Zagreb, Croatia, Yugoslavia
J. M. Jerkunica
; Institute »Ruder Boskovic«, 41000 Zagreb, Croatia, Yugoslavia
L. Klasinc
; Institute »Ruder Boskovic«, 41000 Zagreb, Croatia, Yugoslavia
J. Marsel
; University of Ljubljana, »Jozef Stefan« Institute, 61000 Ljubljana, Slovenia, Yugoslavia
Abstract
The fragmentation of bicyclo[2.2.1]-2-heptanol, endo- (I) and
exo- (Ia), 1-methylbicyclo[2.2.1]-2-heptanol, endo- (II) and exo(
IIa) and 2-methylbicyclo[2.2.1]-2-heptanol, endo- (III) has been
studied by employing the deuterium labelling technique. The
results obtained indicate · that the existence of nonclassical carbonium
ion is of no significant importance during the fragmentation
of the molecular ion of these alcohols and that the
dehydration of the molecular ion is stereospecific regarding the
position of eliminated hydrogen.
Keywords
Hrčak ID:
197268
URI
Publication date:
15.7.1972.
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