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Conference paper

Electrochemical Generation of Solvated Electrons and Hydrogen Evolution in Hexamethylphosphortriamide

L. I. Krishtalik ; Institute of Electrochemistry, Academy of Sciences of the USSR, Moscow, USSR
N. M. Alpatova ; Institute of Electrochemistry, Academy of Sciences of the USSR, Moscow, USSR
M. G. Fomicheva ; Institute of Electrochemistry, Academy of Sciences of the USSR, Moscow, USSR


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Abstract

Electrolysis experiments with rotating disc electrodes of copper,
amalgamated copper, and platinum in anhydrous hexamethylphosphortriamide are described. It is shown that the generation
of solvated electrons is a primary process. In the same
solutions (0.2 M LiCl + 0.09 to 0.20 M HCl) hydrogen evolution
occurs as a direct proton discharge step and not through a reaction
with the solvated electron(s).

Keywords

Hrčak ID:

197280

URI

https://hrcak.srce.hr/197280

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