Original scientific paper

Solvent Extraction of Vanadium (V) with N-Benzoyl-N-phenylhydroxylamine

V. Dražić-Antonijević ; Boris Kidric Institute of Nuclear Sciences and Department of Chemistry, Faculty of Natural Sciences, University of Beograd, Beograd, Serbia, Yugoslavia
V. Vajgand ; Boris Kidric Institute of Nuclear Sciences and Department of Chemistry, Faculty of Natural Sciences, University of Beograd, Beograd, Serbia, Yugoslavia
I. J. Gal ; Boris Kidric Institute of Nuclear Sciences and Department of Chemistry, Faculty of Natural Sciences, University of Beograd, Beograd, Serbia, Yugoslavia

Abstract

N-Benzoyl-N-phenylhydroxylamine is a monomeric solute in
chloroform which readily extracts vot from acidic aqueous solutions.
The vanadium species extracted from concentrated aqueous
acid solutions have a characteristic absorption band at 450-550 mμ.
Solvent extraction experiments indicate that from aqueous 1-6
N HCl two vanadium species are extracted into chloroform. The
compositions of these species correspond to the reagent: vanadium:
chloride ratios of 2 : 1 : 1 and 3 : 1 : 1.

Keywords

Hrčak ID:

207960

URI

https://hrcak.srce.hr/207960

Publication date:

1.8.1969.

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