Croatica Chemica Acta, Vol. 33 No. 3, 1961.
Original scientific paper
Heterogeneous Exchange of Precipitates. IV. Influence of n-decylamine, K-caprinate, AP+ and Co2 + on the Agl-Ag+ Exchange
M. Mirnik
; Institute »Ruder Boskovic« and Laboratory or Physical Ch emistry, F aculty or Science, University of Zagreb, Zagreb, Croatia, Yugoslavia
R. Despotović
; Institute »Ruder Boskovic« and Laboratory or Physical Ch emistry, F aculty or Science, University of Zagreb, Zagreb, Croatia, Yugoslavia
Abstract
0.0025 M n-decyla mine nitrate, 0.001 M K-caprinate, 1 N Ala +_
or Co2+-ni.trates do not measurably influence the process of heterogeneous Agl-Ag+ exchange.
In the discussion the conclusion was reached that the double
layer has to be considered as a structure in which the individuality
of particles is maintained. On the positive Agl the Ag may be present either as Ag a tom in electrochemical equilibrium, as hydrated Ag+-ion, as associated ion pair Ag+ -ion - counter ion or as Ag +-ion in the crystal lattice.
Keywords
Hrčak ID:
208430
URI
Publication date:
15.1.1962.
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