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Original scientific paper

https://doi.org/10.5599/jese.727

Electroactive properties of a new azulene thioxo-imidazolidin-4-one ligand for modified electrodes

Elena Diacu ; University "Politehnica" of Bucharest, Faculty of Applied Chemistry and Material Science, 1-7 Gheorghe Polizu, 011061, Bucharest, Romania
Adinuta Paun ; University "Politehnica" of Bucharest, Faculty of Applied Chemistry and Material Science, 1-7 Gheorghe Polizu, 011061, Bucharest, Romania
Veronica Anastasoaie ; University "Politehnica" of Bucharest, Faculty of Applied Chemistry and Material Science, 1-7 Gheorghe Polizu, 011061, Bucharest, Romania
Georgiana-Luiza Arnold-Tatu ; University "Politehnica" of Bucharest, Faculty of Applied Chemistry and Material Science, 1-7 Gheorghe Polizu, 011061, Bucharest, Romania
Liviu Birzan ; Romanian Academy, Institute of Organic Chemistry “C. D. Nenitzescu”, Spl. Independentei, 202B, 060023-Bucharest, 35 P.O. Box 108, Romania
Eleonora-Mihaela Ungureanu ; University "Politehnica" of Bucharest, Faculty of Applied Chemistry and Material Science, 1-7 Gheorghe Polizu, 011061, Bucharest, Romania


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Abstract

The electrochemical characterization of a new synthesized azulene compound (Z)-5-((5-isopropyl-3,8-dimethylazulen-1-yl)methylene)-2-thioxoimidazolidin-4-one (L) using cyclic voltammetry, differential pulse voltammetry and rotating disk electrode is presented. Chemically modified electrodes were obtained by successive scanning or by controlled potential electrolysis using different electrode potentials or charges. The new modified electrodes were tested in solutions containing different concentrations of the following heavy metals:
cadmium, lead, mercury and copper. A good analytical response was obtained for Pb2+.

Keywords

(Z)-5-((5-isopropyl-3,8-dimethylazulen-1-yl)methylene)-2-thioxo-imidazolidin-4-one; electrochemical characterization; chemically modified electrodes; heavy metals recognition

Hrčak ID:

235507

URI

https://hrcak.srce.hr/235507

Publication date:

10.3.2020.

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