Croatica Chemica Acta, Vol. 30 No. 1, 1958.
Short communication, Note
A Polarographic Study of the Monocarboxylato Complexes of Lead
V. Klemenčić
; Institute of Inorganic Chemistry, Faculty of Technology, University of Zagreb, Zagreb, Croatia, Yugoslavia
I. Filipović
; Institute of Inorganic Chemistry, Faculty of Technology, University of Zagreb, Zagreb, Croatia, Yugoslavia
Abstract
The formation of monocarboxylato complexes of lead has been investigated by polarographic method in aqueous solutions containing excess of sodium formate, acetate, propionate, butyrate, n - valerate, iso-valerate, monochloracetate, and glycollate, respectively. The concentrations of monocarboxylate ions have been ranged from 0 to 3M. To avoid the hydrolysis of monocarboxylato complexes, the solutions contained a constant concentration (2 M) of the corresponding monocarboxylic acid, and, in the case of less soluble valeric acids, 200/o of free acid.
Keywords
Hrčak ID:
245627
URI
Publication date:
25.3.1958.
Visits: 564 *