Original scientific paper

Studies on the Compounds of the Group V Elements with Mercury II. On the Mercury arseno-iodide Hg3As2I4 and Mercury antimono-iodide Hg3Sb2l4

D. Grdenić ; Laboratory for General and Inorganic Chemistry, Faculty of Science, University of Zagreb, Zagreb, Croatia, Yugoslavia
K. Strunjak ; Laboratory for General and Inorganic Chemistry, Faculty of Science, University of Zagreb, Zagreb, Croatia, Yugoslavia
H. Dedić ; Laboratory for General and Inorganic Chemistry, Faculty of Science, University of Zagreb, Zagreb, Croatia, Yugoslavia

Abstract

The preparation, analysis and properties of the compounds Hg3As2I4 and Hg3Sb2I4 are described for the first time. The compounds were prepared in pure state by the action of metallic mercury on arsenic- and antimony triiodide respectively; they are well defined crystalline substances. The chemical reactions described show that these compounds probably belong to the class of arsonium and stibonium compounds but the other possibilities are not excluded.

Keywords

Hrčak ID:

247924

URI

https://hrcak.srce.hr/247924

Publication date:

1.7.1955.

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