Croatica Chemica Acta, Vol. 27 No. 1, 1955.
Original scientific paper
Treatment of Polarographic Data by the Method of Least-squares. II. Simultaneous Estimation of the Diffusion Current and the Half-wave Potential
V. B. Vouk
; Institute for Medical Research, Yugoslav Academy of Sciences and Arts, Zagreb, Croatia, Yugoslavia
P. K. Karmalkar
; Institute for Medical Research, Yugoslav Academy of Sciences and Arts, Zagreb, Croatia, Yugoslavia
O. A. Weber
; Institute for Medical Research, Yugoslav Academy of Sciences and Arts, Zagreb, Croatia, Yugoslavia
Abstract
By applying the method of least squares it is possible to estimate simultaneously the diffusion current and the half-wave potential with precision which exceeds that of the usual graphical methods. The method described in this paper is particularly suitable for analysing composite current-voltage curves. An example is given of the analysis of the composite curve obtained with a solution containing thallous and lead ions in 0.1 N KCL
Keywords
Hrčak ID:
249395
URI
Publication date:
1.5.1955.
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