Original scientific paper

Methorics of the Precipitation Processes. XI. The Complex Solubility of Silver Halides and Silver Thiocyanate in Mixed Solvents

J. Kratohvil ; Applied Chemistry Laboratory, School of Public Health, and Laboratory of Physical Chemistry, Faculty of Science, University of Zagreb, Croatia, Yugoslavia
B. Težak ; Applied Chemistry Laboratory, School of Public Health, and Laboratory of Physical Chemistry, Faculty of Science, University of Zagreb, Croatia, Yugoslavia

Abstract

The complex solubility of silver chloride, bromide, iodide, and thiocyanate in halide or thiocyanate solutions in isodielectric mixtures of water-methanol, water-ethanol and water-acetone was determined. Complex solubility of these precipitates increased, in regard to water, with increasing concentration of the organic component in solutions. The increase of complex solubility was nearly the same for water-methanol and water-ethanol mixtures of the same dielectric constant, but the change of complex solubility in corresponding water-acetone mixtures was much greater.

Keywords

Hrčak ID:

249405

URI

https://hrcak.srce.hr/249405

Publication date:

31.1.1955.

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