Croatica Chemica Acta, Vol. 21 No. 1-4, 1949.
Original scientific paper
Methorics of the precipitacion processes I. Some concepts of the crystal growth from electrolytic solutions
B. Težak
; Fizičko-kemijski institut, Prirodoslovni fakultet Zagreb
Abstract
It is emphaisized that in discussing the elementary process of ionic crystal growth, the structure of the region between the crystal phase and the ionic solution must be duly considered. These intermediate structures are influenced by both weII defined phases of the boundary region, and have many specific properties. In order to visualze the principal elements of these transitional, typically methorical structures, some elements of Bjerrum's theory of ionic association are used, and the concept of the probability spheres and probability shells indicating the probability of free, dissociated or associated ionic states respectively, is introduced.
Keywords
Hrčak ID:
257578
URI
Publication date:
1.9.1950.
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