Croatica Chemica Acta, Vol. 85 No. 4, 2012.
Izvorni znanstveni članak
https://doi.org/10.5562/cca2126
Theory of Square-wave Voltammetry of Kinetically Controlled Two-step Electrode Reactions
Milivoj Lovrić
; Department of Marine and Environmental Research, “Ruđer Bošković” Institute, 10000 Zagreb, Croatia
Šebojka Komorsky-Lovrić
; Department of Marine and Environmental Research, “Ruđer Bošković” Institute, 10000 Zagreb, Croatia
Sažetak
An influence of electron transfer kinetics on square-wave voltammograms of two-step electrode reaction is investigated theoretically. A phenomenon of “kinetic burden” of potential inversion is described for the case of equal kinetic parameters. A linear relationship between standard rate constant and the difference between standard potentials of the second and the first charge transfers is demonstrated for the reactions with thermodynamically unstable intermediate. (doi: 10.5562/cca2126)
Ključne riječi
square-wave voltammetry; kinetics of electrode reaction; two-step electrode reaction; intermediate; standard rate constant
Hrčak ID:
94468
URI
Datum izdavanja:
17.12.2012.
Posjeta: 2.832 *