Croatica Chemica Acta, Vol. 86 No. 4, 2013.
Izvorni znanstveni članak
https://doi.org/10.5562/cca2304
Borane Polyhedra as Building Blocks for Unknown but Potentially Isolatable New Molecules – Extensions based on Computations of the Known B18H22 Isomers
Josep M. Oliva
; Instituto de Química-Física “Rocasolano”, CSIC, 28006 Madrid, Spain
Juanjo Rué
; Instituto de Ciencias Matemáticas (CSIC – UAM – UC3M – UCM), Universidad Autónoma de Madrid, 28049 Madrid, Spain
John D. Kennedy
; Institute of Inorganic Chemistry of the AS CR, v.v.i., 250 68 Husinec-Řež, Czech Republic;The School of Chemistry of the University of Leeds, Leeds LS2 9JT, UK
Vladimir R. Rosenfeld
; Texas A&M University, Galveston, TX 77553, USA
Sažetak
Known borane polyhedral cluster characteristics can be used for predicting new architectural
constructs. We propose additional structures derived from B18H22 : three positional isomers different from
the well-known anti-B18H22 and syn-B18H22 boranes. We have also derived two new cyclic structures
based on the condensation of borane pentagonal pyramids and bipyramids. The concatenation of polyhedral
borane molecules is also considered from a mathematical point of view. (doi: 10.5562/cca2304)
Ključne riječi
boranes; bond; B18H22; quantum chemistry; mathematical chemistry
Hrčak ID:
112785
URI
Datum izdavanja:
16.12.2013.
Posjeta: 2.083 *