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The Chemistry of Carbonyl Cyanide. Dienophilic Properties of Carbonyl Cyanide and Diethyl Mesoxalate. Formation of Dihydropyran Derivatives

O. Achmatowicz ; Department of Organic Chemistry, Warsaw University
A. Zamojski ; Department of Organic Chemistry, Warsaw University


Puni tekst: engleski pdf 8.313 Kb

str. 269-275

preuzimanja: 256

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Sažetak

The reactions of carbonyl cyanide with butadiene or 2,3-dimethylbutadiene have been studoied. In either case there was found to take place diene condensation leading to corresponding derivatives of dihydropyran. Dihydropyran derivatives synthesis was also found to occur when die thylmesoxalate was condensed with the dienes. The correctness of the structure of the adducts obtained was established by degradation experiments.

Ključne riječi

Hrčak ID:

246079

URI

https://hrcak.srce.hr/246079

Datum izdavanja:

30.12.1957.

Posjeta: 703 *