APA 6th Edition Marciuš, M., Ristić, M., Ivanda, M. i Musić, S. (2012). Formation of Iron Oxides by Surface Oxidation of Iron Plate. Croatica Chemica Acta, 85 (1), 117-124. https://doi.org/10.5562/cca1943
MLA 8th Edition Marciuš, Marijan, et al. "Formation of Iron Oxides by Surface Oxidation of Iron Plate." Croatica Chemica Acta, vol. 85, br. 1, 2012, str. 117-124. https://doi.org/10.5562/cca1943. Citirano 04.03.2021.
Chicago 17th Edition Marciuš, Marijan, Mira Ristić, Mile Ivanda i Svetozar Musić. "Formation of Iron Oxides by Surface Oxidation of Iron Plate." Croatica Chemica Acta 85, br. 1 (2012): 117-124. https://doi.org/10.5562/cca1943
Harvard Marciuš, M., et al. (2012). 'Formation of Iron Oxides by Surface Oxidation of Iron Plate', Croatica Chemica Acta, 85(1), str. 117-124. https://doi.org/10.5562/cca1943
Vancouver Marciuš M, Ristić M, Ivanda M, Musić S. Formation of Iron Oxides by Surface Oxidation of Iron Plate. Croatica Chemica Acta [Internet]. 2012 [pristupljeno 04.03.2021.];85(1):117-124. https://doi.org/10.5562/cca1943
IEEE M. Marciuš, M. Ristić, M. Ivanda i S. Musić, "Formation of Iron Oxides by Surface Oxidation of Iron Plate", Croatica Chemica Acta, vol.85, br. 1, str. 117-124, 2012. [Online]. https://doi.org/10.5562/cca1943
Sažetak Oxidation of iron plates (α-phase) at high temperatures and in atmospheric conditions was monitored. The composition of oxidation products was analyzed with XRD, Raman and Mössbauer spectros-copies, whereas the morphologies of oxidation products were inspected by FE-SEM. The oxidation products formed at 300 and 400 °C consisted dominantly of magnetite and small fractions of hematite, whereas at 500 and 600 °C hematite was the dominant phase, as shown by XRD. In all these samples Raman spectra showed the presence of hematite in the outer oxidation layer. FE-SEM analysis showed the formation of nanowires at 500 °C and vertically grown hematite spikes against the lower oxidation layers at 600 °C. Oxidation products formed at 800 °C consisted of wüstite (Fe1–xO) as the dominant phase, nonstoichiometric magnetite (Fe3–xO4) and hematite (α-Fe2O3) in small fractions. The surface of these oxidation layers showed a hierarchical microstructure, as well as the hexagonal hematite rods vertically grown against the lower oxidation layers. The formation of the oxidation products can be considered a process which includes the oxidation of α-Fe to Fe1–xO and its transformation to Fe3–xO4 that further transforms to α-Fe2O3, probably via a short-lived γ-Fe2O3 (maghemite) phase. (doi: 10.5562/cca1943)