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https://doi.org/10.5562/cca2126

Theory of Square-wave Voltammetry of Kinetically Controlled Two-step Electrode Reactions

Milivoj Lovrić ; Department of Marine and Environmental Research, “Ruđer Bošković” Institute, 10000 Zagreb, Croatia
Šebojka Komorsky-Lovrić ; Department of Marine and Environmental Research, “Ruđer Bošković” Institute, 10000 Zagreb, Croatia

Puni tekst: engleski, pdf (2 MB) str. 569-575 preuzimanja: 1.066* citiraj
APA 6th Edition
Lovrić, M. i Komorsky-Lovrić, Š. (2012). Theory of Square-wave Voltammetry of Kinetically Controlled Two-step Electrode Reactions. Croatica Chemica Acta, 85 (4), 569-575. https://doi.org/10.5562/cca2126
MLA 8th Edition
Lovrić, Milivoj i Šebojka Komorsky-Lovrić. "Theory of Square-wave Voltammetry of Kinetically Controlled Two-step Electrode Reactions." Croatica Chemica Acta, vol. 85, br. 4, 2012, str. 569-575. https://doi.org/10.5562/cca2126. Citirano 25.02.2021.
Chicago 17th Edition
Lovrić, Milivoj i Šebojka Komorsky-Lovrić. "Theory of Square-wave Voltammetry of Kinetically Controlled Two-step Electrode Reactions." Croatica Chemica Acta 85, br. 4 (2012): 569-575. https://doi.org/10.5562/cca2126
Harvard
Lovrić, M., i Komorsky-Lovrić, Š. (2012). 'Theory of Square-wave Voltammetry of Kinetically Controlled Two-step Electrode Reactions', Croatica Chemica Acta, 85(4), str. 569-575. https://doi.org/10.5562/cca2126
Vancouver
Lovrić M, Komorsky-Lovrić Š. Theory of Square-wave Voltammetry of Kinetically Controlled Two-step Electrode Reactions. Croatica Chemica Acta [Internet]. 2012 [pristupljeno 25.02.2021.];85(4):569-575. https://doi.org/10.5562/cca2126
IEEE
M. Lovrić i Š. Komorsky-Lovrić, "Theory of Square-wave Voltammetry of Kinetically Controlled Two-step Electrode Reactions", Croatica Chemica Acta, vol.85, br. 4, str. 569-575, 2012. [Online]. https://doi.org/10.5562/cca2126

Sažetak
An influence of electron transfer kinetics on square-wave voltammograms of two-step electrode reaction is investigated theoretically. A phenomenon of “kinetic burden” of potential inversion is described for the case of equal kinetic parameters. A linear relationship between standard rate constant and the difference between standard potentials of the second and the first charge transfers is demonstrated for the reactions with thermodynamically unstable intermediate. (doi: 10.5562/cca2126)

Ključne riječi
square-wave voltammetry; kinetics of electrode reaction; two-step electrode reaction; intermediate; standard rate constant

Hrčak ID: 94468

URI
https://hrcak.srce.hr/94468

Posjeta: 1.437 *