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Croatica Chemica Acta, Vol.77 No.1-2 May 2004.

Original scientific paper

Isotope Effect in the Gas Phase Reaction of Pyrene-d10 with Nb+ Ions

Saša Kazazić ; Laboratory for Chemical Kinetics and Atmospheric Chemistry, Rugjer Bošković Institute, HR-10002 Zagreb, Croatia
Leo Klasinc ; Laboratory for Chemical Kinetics and Atmospheric Chemistry, Rugjer Bošković Institute, HR-10002 Zagreb, Croatia
Marko Rožman ; Laboratory for Chemical Kinetics and Atmospheric Chemistry, Rugjer Bošković Institute, HR-10002 Zagreb, Croatia
Dunja Srzić ; Laboratory for Chemical Kinetics and Atmospheric Chemistry, Rugjer Bošković Institute, HR-10002 Zagreb, Croatia
Jan von Knop ; Rechenzentrum der Universität Düsseldorf, D-2 Düsseldorf, Germany

Fulltext: english, pdf (73 KB) pages 321-324 downloads: 189* cite
APA 6th Edition
Kazazić, S., Klasinc, L., Rožman, M., Srzić, D. & von Knop, J. (2004). Isotope Effect in the Gas Phase Reaction of Pyrene-d10 with Nb+ Ions. Croatica Chemica Acta, 77 (1-2), 321-324. Retrieved from https://hrcak.srce.hr/102723
MLA 8th Edition
Kazazić, Saša, et al. "Isotope Effect in the Gas Phase Reaction of Pyrene-d10 with Nb+ Ions." Croatica Chemica Acta, vol. 77, no. 1-2, 2004, pp. 321-324. https://hrcak.srce.hr/102723. Accessed 17 Dec. 2018.
Chicago 17th Edition
Kazazić, Saša, Leo Klasinc, Marko Rožman, Dunja Srzić and Jan von Knop. "Isotope Effect in the Gas Phase Reaction of Pyrene-d10 with Nb+ Ions." Croatica Chemica Acta 77, no. 1-2 (2004): 321-324. https://hrcak.srce.hr/102723
Harvard
Kazazić, S., et al. (2004). 'Isotope Effect in the Gas Phase Reaction of Pyrene-d10 with Nb+ Ions', Croatica Chemica Acta, 77(1-2), pp. 321-324. Available at: https://hrcak.srce.hr/102723 (Accessed 17 December 2018)
Vancouver
Kazazić S, Klasinc L, Rožman M, Srzić D, von Knop J. Isotope Effect in the Gas Phase Reaction of Pyrene-d10 with Nb+ Ions. Croatica Chemica Acta [Internet]. 2004 [cited 2018 December 17];77(1-2):321-324. Available from: https://hrcak.srce.hr/102723
IEEE
S. Kazazić, L. Klasinc, M. Rožman, D. Srzić and J. von Knop, "Isotope Effect in the Gas Phase Reaction of Pyrene-d10 with Nb+ Ions", Croatica Chemica Acta, vol.77, no. 1-2, pp. 321-324, 2004. [Online]. Available: https://hrcak.srce.hr/102723. [Accessed: 17 December 2018]

Abstracts
The deuterium isotope effect in the gas phase ligation of niobium (Nb) monocations by a mixture of pyrene and perdeutero pyrene was studied in a FTMS instrument. The attachment of pyrene (pyrene-d10) is followed by a rapid release of hydrogen (deuterium) from the Nb-pyrene (Nb-pyrene-d10) cation, respectively. The dehydrogenated product formation depends on the experimental conditions in the reaction chamber. A 1,2-elimination of H2 (D2) from the ligation product is proposed.

Keywords
gas phase reaction; Fourier transform mass spectrometry; deuterium kinetic isotope effect; niobium (II); pyrene; pyrene-d10

Hrčak ID: 102723

URI
https://hrcak.srce.hr/102723

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