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Ferrocene Compounds. XXXV. Reactions of 1,1'-Ferrocenylenebis(carbinyl acetate) and Derived Quaternary Iodide with Hydroxyalkanoates

Veronika Kovač ; Faculty of Food Technology and Biotechnology, University of Zagreb, 10000 Zagreb, Croatia
Vladimir Rapić ; Faculty of Food Technology and Biotechnology, University of Zagreb, 10000 Zagreb, Croatia

Puni tekst: engleski, pdf (227 KB) str. 101-105 preuzimanja: 181* citiraj
APA 6th Edition
Kovač, V. i Rapić, V. (2003). Ferrocene Compounds. XXXV. Reactions of 1,1'-Ferrocenylenebis(carbinyl acetate) and Derived Quaternary Iodide with Hydroxyalkanoates. Croatica Chemica Acta, 76 (1), 101-105. Preuzeto s https://hrcak.srce.hr/103078
MLA 8th Edition
Kovač, Veronika i Vladimir Rapić. "Ferrocene Compounds. XXXV. Reactions of 1,1'-Ferrocenylenebis(carbinyl acetate) and Derived Quaternary Iodide with Hydroxyalkanoates." Croatica Chemica Acta, vol. 76, br. 1, 2003, str. 101-105. https://hrcak.srce.hr/103078. Citirano 26.02.2021.
Chicago 17th Edition
Kovač, Veronika i Vladimir Rapić. "Ferrocene Compounds. XXXV. Reactions of 1,1'-Ferrocenylenebis(carbinyl acetate) and Derived Quaternary Iodide with Hydroxyalkanoates." Croatica Chemica Acta 76, br. 1 (2003): 101-105. https://hrcak.srce.hr/103078
Harvard
Kovač, V., i Rapić, V. (2003). 'Ferrocene Compounds. XXXV. Reactions of 1,1'-Ferrocenylenebis(carbinyl acetate) and Derived Quaternary Iodide with Hydroxyalkanoates', Croatica Chemica Acta, 76(1), str. 101-105. Preuzeto s: https://hrcak.srce.hr/103078 (Datum pristupa: 26.02.2021.)
Vancouver
Kovač V, Rapić V. Ferrocene Compounds. XXXV. Reactions of 1,1'-Ferrocenylenebis(carbinyl acetate) and Derived Quaternary Iodide with Hydroxyalkanoates. Croatica Chemica Acta [Internet]. 2003 [pristupljeno 26.02.2021.];76(1):101-105. Dostupno na: https://hrcak.srce.hr/103078
IEEE
V. Kovač i V. Rapić, "Ferrocene Compounds. XXXV. Reactions of 1,1'-Ferrocenylenebis(carbinyl acetate) and Derived Quaternary Iodide with Hydroxyalkanoates", Croatica Chemica Acta, vol.76, br. 1, str. 101-105, 2003. [Online]. Dostupno na: https://hrcak.srce.hr/103078. [Citirano: 26.02.2021.]

Sažetak
Biscarbinol, 1,1'-Fn[CH(CH3)OH)]2 (1), and the corresponding bis(carbinyl acetate) 2 were prepared according to the described procedures. Amination of bisacetate 2 with Me2NH and subsequent quaternization of the intermediate amine 3 gave iodide 4. By the action of alkoxides derived from methyl glycolate and methyl lactate on acetate 2 or salt 4, unsaturated ether 5 (8–22 %), unsaturated esters 6a (6b) (2–18 %) and ester-ethers 7a (7b) (6–15 %) were obtained. The structure of heteroannularly substituted nonsymmetric ferrocene derivatives 5–7 was undoubtedly confirmed by elemental and spectroscopic analyses, and the reaction mechanisms of their formation were proposed.

Ključne riječi
α,α'-(1,1'-ferrocenylene)bisethanol; α,α'-(1,1'-ferrocenylene)bis(ethyl; acetate) and derived quaternary iodide; methyl glycolate; methyl lactate

Hrčak ID: 103078

URI
https://hrcak.srce.hr/103078

Posjeta: 293 *