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The Synthesis and Crystal Structures of 7-Bromo-1,3-dihydro-1-methyl-3(S)-methyl-5-(2'-pyridyl)-2H-1,4-benzodiazepin-2-one and Its CuII Complex

Aleksandar Višnjevac ; Ruđer Bošković Institute, P.O.B. 180, HR-10002 Croatia
Ljerka Tušek-Božić ; Ruđer Bošković Institute, P.O.B. 180, HR-10002 Croatia
Dragan Šepac ; Ruđer Bošković Institute, P.O.B. 180, HR-10002 Croatia
Zdenko Hameršak ; Ruđer Bošković Institute, P.O.B. 180, HR-10002 Croatia
Biserka Kojić-Prodić ; Ruđer Bošković Institute, P.O.B. 180, HR-10002 Croatia

Puni tekst: engleski, pdf (233 KB) str. 107-112 preuzimanja: 267* citiraj
APA 6th Edition
Višnjevac, A., Tušek-Božić, Lj., Šepac, D., Hameršak, Z. i Kojić-Prodić, B. (2003). The Synthesis and Crystal Structures of 7-Bromo-1,3-dihydro-1-methyl-3(S)-methyl-5-(2'-pyridyl)-2H-1,4-benzodiazepin-2-one and Its CuII Complex. Croatica Chemica Acta, 76 (1), 107-112. Preuzeto s https://hrcak.srce.hr/103079
MLA 8th Edition
Višnjevac, Aleksandar, et al. "The Synthesis and Crystal Structures of 7-Bromo-1,3-dihydro-1-methyl-3(S)-methyl-5-(2'-pyridyl)-2H-1,4-benzodiazepin-2-one and Its CuII Complex." Croatica Chemica Acta, vol. 76, br. 1, 2003, str. 107-112. https://hrcak.srce.hr/103079. Citirano 09.03.2021.
Chicago 17th Edition
Višnjevac, Aleksandar, Ljerka Tušek-Božić, Dragan Šepac, Zdenko Hameršak i Biserka Kojić-Prodić. "The Synthesis and Crystal Structures of 7-Bromo-1,3-dihydro-1-methyl-3(S)-methyl-5-(2'-pyridyl)-2H-1,4-benzodiazepin-2-one and Its CuII Complex." Croatica Chemica Acta 76, br. 1 (2003): 107-112. https://hrcak.srce.hr/103079
Harvard
Višnjevac, A., et al. (2003). 'The Synthesis and Crystal Structures of 7-Bromo-1,3-dihydro-1-methyl-3(S)-methyl-5-(2'-pyridyl)-2H-1,4-benzodiazepin-2-one and Its CuII Complex', Croatica Chemica Acta, 76(1), str. 107-112. Preuzeto s: https://hrcak.srce.hr/103079 (Datum pristupa: 09.03.2021.)
Vancouver
Višnjevac A, Tušek-Božić Lj, Šepac D, Hameršak Z, Kojić-Prodić B. The Synthesis and Crystal Structures of 7-Bromo-1,3-dihydro-1-methyl-3(S)-methyl-5-(2'-pyridyl)-2H-1,4-benzodiazepin-2-one and Its CuII Complex. Croatica Chemica Acta [Internet]. 2003 [pristupljeno 09.03.2021.];76(1):107-112. Dostupno na: https://hrcak.srce.hr/103079
IEEE
A. Višnjevac, Lj. Tušek-Božić, D. Šepac, Z. Hameršak i B. Kojić-Prodić, "The Synthesis and Crystal Structures of 7-Bromo-1,3-dihydro-1-methyl-3(S)-methyl-5-(2'-pyridyl)-2H-1,4-benzodiazepin-2-one and Its CuII Complex", Croatica Chemica Acta, vol.76, br. 1, str. 107-112, 2003. [Online]. Dostupno na: https://hrcak.srce.hr/103079. [Citirano: 09.03.2021.]

Sažetak
By reaction of the enantiomerically pure 7-bromo-1,3-dihydro-1-methyl-3(S)-methyl-5-(2'-pyridyl)-2H-1,4-benzodiazepin-2-one, (+)-1, with CuCl2 ∙ 2H2O in a mixture of absolute ethanol and dichloromethane, dichloro-[7-bromo-1,3-dihydro-1,3-dimethyl-5-(2'-pyridyl)-2H-1,4-benzodiazepin-2-on-N,N,O]copper(II), (±)-2, was obtained. In both structures, the characteristic boat conformation of the seven-membered benzodiazepine ring was observed. Complex 2, which was isolated as a racemic compound, revealed a slightly distorted trigonal bipyramid. Copper(II) was coordinated by two azometine nitrogen atoms, two chlorine atoms and the lactam oxygen of a neighbouring molecule. In this way, an infinite chain of complex molecules was formed in the crystal. The chemical behaviour of ligand 1 upon CuII coordination was compared with its 3-hydroxymethyl and 3-acetoxymethyl analogues.

Ključne riječi
chiral 1,4-benzodiazepine; copper complex; synthesis; crystal structure

Hrčak ID: 103079

URI
https://hrcak.srce.hr/103079

Posjeta: 432 *