hrcak mascot   Srce   HID

Izvorni znanstveni članak
https://doi.org/10.5562/cca2298

Lattice Enthalpies of Lanthanide Orthovanadates LnVO4

Dimitar Petrov   ORCID icon orcid.org/0000-0002-5709-3039 ; Department of Physical Chemistry, Plovdiv University, 24, Tsar Asen Str., 4000 Plovdiv, Bulgaria

Puni tekst: engleski, pdf (1 MB) str. 85-89 preuzimanja: 714* citiraj
APA 6th Edition
Petrov, D. (2014). Lattice Enthalpies of Lanthanide Orthovanadates LnVO4. Croatica Chemica Acta, 87 (1), 85-89. https://doi.org/10.5562/cca2298
MLA 8th Edition
Petrov, Dimitar. "Lattice Enthalpies of Lanthanide Orthovanadates LnVO4." Croatica Chemica Acta, vol. 87, br. 1, 2014, str. 85-89. https://doi.org/10.5562/cca2298. Citirano 15.06.2021.
Chicago 17th Edition
Petrov, Dimitar. "Lattice Enthalpies of Lanthanide Orthovanadates LnVO4." Croatica Chemica Acta 87, br. 1 (2014): 85-89. https://doi.org/10.5562/cca2298
Harvard
Petrov, D. (2014). 'Lattice Enthalpies of Lanthanide Orthovanadates LnVO4', Croatica Chemica Acta, 87(1), str. 85-89. https://doi.org/10.5562/cca2298
Vancouver
Petrov D. Lattice Enthalpies of Lanthanide Orthovanadates LnVO4. Croatica Chemica Acta [Internet]. 2014 [pristupljeno 15.06.2021.];87(1):85-89. https://doi.org/10.5562/cca2298
IEEE
D. Petrov, "Lattice Enthalpies of Lanthanide Orthovanadates LnVO4", Croatica Chemica Acta, vol.87, br. 1, str. 85-89, 2014. [Online]. https://doi.org/10.5562/cca2298

Sažetak
Lattice enthalpies ΔLH° of lanthanide orthovanadates, LnVO4 (Ln = Ce - Lu, except Pm) have been deter-mined from the Born-Haber thermochemical cycle and compared with those calculated by an empirical equation. Two different sets of enthalpies of formation of LnVO4, from oxides (Ln2O3, V2O5) and from elements, have been used but the differences in ΔLH° are small. The Born-Haber cycle in both routes yields close values of ΔLH° to those obtained after an empirical equation proposed by Glasser and Jenkins. It has been found that the partial derivative of the lattice enthalpies to the molar volumes corresponds by magnitude and dimension to the shear moduli of these crystals. (doi: 10.5562/cca2298)

Ključne riječi
lattice enthalpies; lanthanide orthovanadates; shear moduli; thermochemistry; Born-Haber cycle

Hrčak ID: 122284

URI
https://hrcak.srce.hr/122284

Posjeta: 1.031 *