hrcak mascot   Srce   HID

Izvorni znanstveni članak

Linear Free Energy Relationships near Isokinetic Temperature. Oxidation of Organic Sulfides with Nicotinium Dichromate

Chockalingam Karunakaran ; Department of Chemistry, Annamalai University, Annamalainagar 608 002, India
Vaithijalingam Chidambaranathan ; Department of Chemistry, Annamalai University, Annamalainagar 608 002, India

Puni tekst: engleski, pdf (71 KB) str. 51-59 preuzimanja: 409* citiraj
APA 6th Edition
Karunakaran, C. i Chidambaranathan, V. (2001). Linear Free Energy Relationships near Isokinetic Temperature. Oxidation of Organic Sulfides with Nicotinium Dichromate. Croatica Chemica Acta, 74 (1), 51-59. Preuzeto s https://hrcak.srce.hr/131766
MLA 8th Edition
Karunakaran, Chockalingam i Vaithijalingam Chidambaranathan. "Linear Free Energy Relationships near Isokinetic Temperature. Oxidation of Organic Sulfides with Nicotinium Dichromate." Croatica Chemica Acta, vol. 74, br. 1, 2001, str. 51-59. https://hrcak.srce.hr/131766. Citirano 07.03.2021.
Chicago 17th Edition
Karunakaran, Chockalingam i Vaithijalingam Chidambaranathan. "Linear Free Energy Relationships near Isokinetic Temperature. Oxidation of Organic Sulfides with Nicotinium Dichromate." Croatica Chemica Acta 74, br. 1 (2001): 51-59. https://hrcak.srce.hr/131766
Harvard
Karunakaran, C., i Chidambaranathan, V. (2001). 'Linear Free Energy Relationships near Isokinetic Temperature. Oxidation of Organic Sulfides with Nicotinium Dichromate', Croatica Chemica Acta, 74(1), str. 51-59. Preuzeto s: https://hrcak.srce.hr/131766 (Datum pristupa: 07.03.2021.)
Vancouver
Karunakaran C, Chidambaranathan V. Linear Free Energy Relationships near Isokinetic Temperature. Oxidation of Organic Sulfides with Nicotinium Dichromate. Croatica Chemica Acta [Internet]. 2001 [pristupljeno 07.03.2021.];74(1):51-59. Dostupno na: https://hrcak.srce.hr/131766
IEEE
C. Karunakaran i V. Chidambaranathan, "Linear Free Energy Relationships near Isokinetic Temperature. Oxidation of Organic Sulfides with Nicotinium Dichromate", Croatica Chemica Acta, vol.74, br. 1, str. 51-59, 2001. [Online]. Dostupno na: https://hrcak.srce.hr/131766. [Citirano: 07.03.2021.]

Sažetak
The nicotinium dichromate (NDC) oxidation of methyl phenyl sulfide (MeSPh) in acetonitrile, brought about by p-toluenesulfonic acid (TsOH), is first order in NDC and TsOH, and is zero order with respect to MeSPh in the concentration range investigated. The NDC oxidation of 14 para-, meta- and ortho-substituted phenyl methyl sulfides at 293-318 K complies with the isokinetic relationship but not to any of the linear free energy relationships; the isokinetic temperature lies within the experimental temperature range.

Ključne riječi
linear free energy relationships; activation parameters; isokinetic temperature

Hrčak ID: 131766

URI
https://hrcak.srce.hr/131766

Posjeta: 539 *