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Results of Hydrothermal Treatment of the Amorphous Phases Obtained by Ball Milling of Zeolites A, X and Synthetic Mordenite

Cleo Kosanović ; Ruđer Bošković Institute, P. O. Box 180, 10002 Zagreb, Croatia
Boris Subotić ; Ruđer Bošković Institute, P. O. Box 180, 10002 Zagreb, Croatia
Ivan Šmit ; Ruđer Bošković Institute, P. O. Box 180, 10002 Zagreb, Croatia

Puni tekst: engleski, pdf (158 KB) str. 195-206 preuzimanja: 220* citiraj
APA 6th Edition
Kosanović, C., Subotić, B. i Šmit, I. (2001). Results of Hydrothermal Treatment of the Amorphous Phases Obtained by Ball Milling of Zeolites A, X and Synthetic Mordenite. Croatica Chemica Acta, 74 (1), 195-206. Preuzeto s https://hrcak.srce.hr/131789
MLA 8th Edition
Kosanović, Cleo, et al. "Results of Hydrothermal Treatment of the Amorphous Phases Obtained by Ball Milling of Zeolites A, X and Synthetic Mordenite." Croatica Chemica Acta, vol. 74, br. 1, 2001, str. 195-206. https://hrcak.srce.hr/131789. Citirano 08.03.2021.
Chicago 17th Edition
Kosanović, Cleo, Boris Subotić i Ivan Šmit. "Results of Hydrothermal Treatment of the Amorphous Phases Obtained by Ball Milling of Zeolites A, X and Synthetic Mordenite." Croatica Chemica Acta 74, br. 1 (2001): 195-206. https://hrcak.srce.hr/131789
Harvard
Kosanović, C., Subotić, B., i Šmit, I. (2001). 'Results of Hydrothermal Treatment of the Amorphous Phases Obtained by Ball Milling of Zeolites A, X and Synthetic Mordenite', Croatica Chemica Acta, 74(1), str. 195-206. Preuzeto s: https://hrcak.srce.hr/131789 (Datum pristupa: 08.03.2021.)
Vancouver
Kosanović C, Subotić B, Šmit I. Results of Hydrothermal Treatment of the Amorphous Phases Obtained by Ball Milling of Zeolites A, X and Synthetic Mordenite. Croatica Chemica Acta [Internet]. 2001 [pristupljeno 08.03.2021.];74(1):195-206. Dostupno na: https://hrcak.srce.hr/131789
IEEE
C. Kosanović, B. Subotić i I. Šmit, "Results of Hydrothermal Treatment of the Amorphous Phases Obtained by Ball Milling of Zeolites A, X and Synthetic Mordenite", Croatica Chemica Acta, vol.74, br. 1, str. 195-206, 2001. [Online]. Dostupno na: https://hrcak.srce.hr/131789. [Citirano: 08.03.2021.]

Sažetak
High-energy ball milling of zeolites A, X and synthetic mordenite for an appropriate time results in the formation of true amorphous aluminosilicate phases having the same Chemical composition as the starting (unmilled) crystalline materials (zeolites). Since the solubility of thus prepared amorphous solids in hot alkaline Solutions is considerably higher than the solubility of the starting zeolites under the same conditions, it can be expected that hydro-thermal treatment of the amorphous solids would result in their transformation to more stable phases by solution-mediated processes. To evaluate this thesis, the X-ray amorphous solid phases obtained by high-energy ball milling of zeolites A, X and synthetic mordenite were hydrothermally treated at 80 °C by 2 M and 4 M NaOH solution, respectively, for 4 h. The products obtained (zeolites A, P and hydroxysodalite) were characterized by X-ray powder diffraction and particle size distribution measurements. It was concluded that the nuclei for zeolite crystallization originate from the residual nano-sized quasicrystalline particles (short-range ordering of Si and Al atoms inside amorphous regions that have not been completely destroyed during milling). Type(s) of the zeolite(s) (zeolite A, zeolite P2) crystallized by the growth of the nuclei under the given conditions are determined by the Chemical composition of the liquid phase (concentrations of Si and Al), and by the Chemical composition of the precursor (determined by the type of mechano-chemically amorphized zeolite) and the alkalinity of the system (NaOH concentration in the liquid phase), respectively. The results obtained are in agreement with the thermodynamic stabilities of the zeolite types that may be crystallized under the given conditions and at relative rates of crystallization.

Ključne riječi
zeolite A; zeolite X; synthetic mordenite; amorphization; bali milling; hydrothermal treatment; transformation

Hrčak ID: 131789

URI
https://hrcak.srce.hr/131789

Posjeta: 364 *