hrcak mascot   Srce   HID

Izvorni znanstveni članak

Effect of Some Macrocyclic Ligands on the Rate of Reduction of Perchlorate Ion by Titanium(III)

Giulio A. Amadei ; Department of Chemistry, Georgetoivn University, Washington DC 20057, USA
Joseph E. Earley, Sr. ; Department of Chemistry, Georgetoivn University, Washington DC 20057, USA

Puni tekst: engleski, pdf (86 KB) str. 601-606 preuzimanja: 224* citiraj
APA 6th Edition
Amadei, G.A. i Earley, Sr., J.E. (2001). Effect of Some Macrocyclic Ligands on the Rate of Reduction of Perchlorate Ion by Titanium(III). Croatica Chemica Acta, 74 (3), 601-606. Preuzeto s https://hrcak.srce.hr/131869
MLA 8th Edition
Amadei, Giulio A. i Joseph E. Earley, Sr.. "Effect of Some Macrocyclic Ligands on the Rate of Reduction of Perchlorate Ion by Titanium(III)." Croatica Chemica Acta, vol. 74, br. 3, 2001, str. 601-606. https://hrcak.srce.hr/131869. Citirano 06.03.2021.
Chicago 17th Edition
Amadei, Giulio A. i Joseph E. Earley, Sr.. "Effect of Some Macrocyclic Ligands on the Rate of Reduction of Perchlorate Ion by Titanium(III)." Croatica Chemica Acta 74, br. 3 (2001): 601-606. https://hrcak.srce.hr/131869
Harvard
Amadei, G.A., i Earley, Sr., J.E. (2001). 'Effect of Some Macrocyclic Ligands on the Rate of Reduction of Perchlorate Ion by Titanium(III)', Croatica Chemica Acta, 74(3), str. 601-606. Preuzeto s: https://hrcak.srce.hr/131869 (Datum pristupa: 06.03.2021.)
Vancouver
Amadei GA, Earley, Sr. JE. Effect of Some Macrocyclic Ligands on the Rate of Reduction of Perchlorate Ion by Titanium(III). Croatica Chemica Acta [Internet]. 2001 [pristupljeno 06.03.2021.];74(3):601-606. Dostupno na: https://hrcak.srce.hr/131869
IEEE
G.A. Amadei i J.E. Earley, Sr., "Effect of Some Macrocyclic Ligands on the Rate of Reduction of Perchlorate Ion by Titanium(III)", Croatica Chemica Acta, vol.74, br. 3, str. 601-606, 2001. [Online]. Dostupno na: https://hrcak.srce.hr/131869. [Citirano: 06.03.2021.]

Sažetak
Complexation with cyclam increases the rate of reduction of perchlorate ion by TiIII (in acidic, aqueous, 4 mol dm-3 LiCl Solutions at 25 °C) relative to the rate of the corresponding reduction of Ti3+. A modified cyclam with pendant amine and p-aminobenzyl functional groups is more effective in this regard than is cyclam itself. Both redox reactions are acid catalyzed. The data is consistent with involvement of an intermediate containing two TiIII centers.

Ključne riječi
titanium(III); perchlorate; perchlorate-reduction; cyclam; catalysis; kinetics; dinuclear intermediate; macrocyclic ligands; titanous ion

Hrčak ID: 131869

URI
https://hrcak.srce.hr/131869

Posjeta: 361 *