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Picture of Bonding in Protonated Phosphorus and Arsenic Clusters. Detection of 3-Center Bonds from the Generalized Population Analysis

Roberto Bochicchio ; Departamento de Fisica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria 1428, Buenos Aires, Argentina
Luis Lain ; Departamento de Quimica Fisica, Facultad de Ciencias, Universidad del Pais Vasco, Apdo. 644 E-48080 Bilbao, Spain
Alicia Torre ; Departamento de Quimica Fisica, Facultad de Ciencias, Universidad del Pais Vasco, Apdo. 644 E-48080 Bilbao, Spain
Robert Ponec ; Institute of Chemical Process Fundamentals, Czech Academy of Sciences, Prague 6- Suchdol, Czech Repuhlic

Puni tekst: engleski, pdf (72 KB) str. 1039-1046 preuzimanja: 192* citiraj
APA 6th Edition
Bochicchio, R., Lain, L., Torre, A. i Ponec, R. (2000). Picture of Bonding in Protonated Phosphorus and Arsenic Clusters. Detection of 3-Center Bonds from the Generalized Population Analysis. Croatica Chemica Acta, 73 (4), 1039-1046. Preuzeto s https://hrcak.srce.hr/131986
MLA 8th Edition
Bochicchio, Roberto, et al. "Picture of Bonding in Protonated Phosphorus and Arsenic Clusters. Detection of 3-Center Bonds from the Generalized Population Analysis." Croatica Chemica Acta, vol. 73, br. 4, 2000, str. 1039-1046. https://hrcak.srce.hr/131986. Citirano 19.06.2021.
Chicago 17th Edition
Bochicchio, Roberto, Luis Lain, Alicia Torre i Robert Ponec. "Picture of Bonding in Protonated Phosphorus and Arsenic Clusters. Detection of 3-Center Bonds from the Generalized Population Analysis." Croatica Chemica Acta 73, br. 4 (2000): 1039-1046. https://hrcak.srce.hr/131986
Harvard
Bochicchio, R., et al. (2000). 'Picture of Bonding in Protonated Phosphorus and Arsenic Clusters. Detection of 3-Center Bonds from the Generalized Population Analysis', Croatica Chemica Acta, 73(4), str. 1039-1046. Preuzeto s: https://hrcak.srce.hr/131986 (Datum pristupa: 19.06.2021.)
Vancouver
Bochicchio R, Lain L, Torre A, Ponec R. Picture of Bonding in Protonated Phosphorus and Arsenic Clusters. Detection of 3-Center Bonds from the Generalized Population Analysis. Croatica Chemica Acta [Internet]. 2000 [pristupljeno 19.06.2021.];73(4):1039-1046. Dostupno na: https://hrcak.srce.hr/131986
IEEE
R. Bochicchio, L. Lain, A. Torre i R. Ponec, "Picture of Bonding in Protonated Phosphorus and Arsenic Clusters. Detection of 3-Center Bonds from the Generalized Population Analysis", Croatica Chemica Acta, vol.73, br. 4, str. 1039-1046, 2000. [Online]. Dostupno na: https://hrcak.srce.hr/131986. [Citirano: 19.06.2021.]

Sažetak
In this report we provide a theoretical support for the existence of nonclassical 3-center bonding recently invoked to explain the structure of protonated phosphorus and arsenic X4H+ clusters.For this purpose the electron structure of these clusters was analysed using the formalism of the generalized population analysis, in terms of which the eventual presence of multicenter bonds in a mo-lecule can be directly detected and localized. Our results confirm the presence of 3-center bonding involving X−H−X fragments in these clusters.

Ključne riječi
phosphorus clusters; arsenic clusters; 3-center bonding

Hrčak ID: 131986

URI
https://hrcak.srce.hr/131986

Posjeta: 317 *