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Crystal Structures of Members in Isostructural Series: Prediction of the Crystal Structure of Cs2MnO4 - a p-K2SO4 Type Isomorph

Slobotka Aleksovska ; Institut za hemija, PMF, Univerzitet »Sv. Kiril i Metodij«, Skopje, Macedonia
Vladimir M. Petruševski ; Institut za hemija, PMF, Univerzitet »Sv. Kiril i Metodij«, Skopje, Macedonia
Ljupčo Pejov ; Institut za hemija, PMF, Univerzitet »Sv. Kiril i Metodij«, Skopje, Macedonia

Puni tekst: engleski, pdf (15 MB) str. 1009-1019 preuzimanja: 163* citiraj
APA 6th Edition
Aleksovska, S., Petruševski, V.M. i Pejov, Lj. (1997). Crystal Structures of Members in Isostructural Series: Prediction of the Crystal Structure of Cs2MnO4 - a p-K2SO4 Type Isomorph. Croatica Chemica Acta, 70 (4), 1009-1019. Preuzeto s https://hrcak.srce.hr/135656
MLA 8th Edition
Aleksovska, Slobotka, et al. "Crystal Structures of Members in Isostructural Series: Prediction of the Crystal Structure of Cs2MnO4 - a p-K2SO4 Type Isomorph." Croatica Chemica Acta, vol. 70, br. 4, 1997, str. 1009-1019. https://hrcak.srce.hr/135656. Citirano 30.03.2020.
Chicago 17th Edition
Aleksovska, Slobotka, Vladimir M. Petruševski i Ljupčo Pejov. "Crystal Structures of Members in Isostructural Series: Prediction of the Crystal Structure of Cs2MnO4 - a p-K2SO4 Type Isomorph." Croatica Chemica Acta 70, br. 4 (1997): 1009-1019. https://hrcak.srce.hr/135656
Harvard
Aleksovska, S., Petruševski, V.M., i Pejov, Lj. (1997). 'Crystal Structures of Members in Isostructural Series: Prediction of the Crystal Structure of Cs2MnO4 - a p-K2SO4 Type Isomorph', Croatica Chemica Acta, 70(4), str. 1009-1019. Preuzeto s: https://hrcak.srce.hr/135656 (Datum pristupa: 30.03.2020.)
Vancouver
Aleksovska S, Petruševski VM, Pejov Lj. Crystal Structures of Members in Isostructural Series: Prediction of the Crystal Structure of Cs2MnO4 - a p-K2SO4 Type Isomorph. Croatica Chemica Acta [Internet]. 1997 [pristupljeno 30.03.2020.];70(4):1009-1019. Dostupno na: https://hrcak.srce.hr/135656
IEEE
S. Aleksovska, V.M. Petruševski i Lj. Pejov, "Crystal Structures of Members in Isostructural Series: Prediction of the Crystal Structure of Cs2MnO4 - a p-K2SO4 Type Isomorph", Croatica Chemica Acta, vol.70, br. 4, str. 1009-1019, 1997. [Online]. Dostupno na: https://hrcak.srce.hr/135656. [Citirano: 30.03.2020.]

Sažetak
Recent studies have shown that the crystal structure of members within a group of isostructural compounds may be successfully predicted. The P-K2SO4 group isomorphs of the general formula M2XO4 were chosen as a family of closely related compounds for which accurately refined crystal structures exist. It is shown that the unit cell parameters and the fractional atomic coordinates exhibit systematic variations with both cation and anion size, as well as with the Mulliken charge of the oxygen atom in the tetrahedral anion. It is thus possible to predict the crystal structure of a given member in the series only on the basis of its chemical composition.
The structure of Cs2MnO4 predicted in this way is compared with
the one refined earlier by X-ray diffraction. The agreement be-
tween the structural parameters in both structures is very good.

Hrčak ID: 135656

URI
https://hrcak.srce.hr/135656

Posjeta: 262 *