hrcak mascot   Srce   HID

Pregledni rad

Secondary Deuterium Isotope Effects and Neighboring Group Participation Revisited

Dionis E. Sunko ; Department of Chemistry, Faculty of Science, University of Zagreb, 10000 Zagreb, Croatia

Puni tekst: engleski, pdf (35 MB) str. 1275-1304 preuzimanja: 129* citiraj
APA 6th Edition
Sunko, D.E. (1996). Secondary Deuterium Isotope Effects and Neighboring Group Participation Revisited. Croatica Chemica Acta, 69 (4), 1275-1304. Preuzeto s https://hrcak.srce.hr/135970
MLA 8th Edition
Sunko, Dionis E.. "Secondary Deuterium Isotope Effects and Neighboring Group Participation Revisited." Croatica Chemica Acta, vol. 69, br. 4, 1996, str. 1275-1304. https://hrcak.srce.hr/135970. Citirano 08.03.2021.
Chicago 17th Edition
Sunko, Dionis E.. "Secondary Deuterium Isotope Effects and Neighboring Group Participation Revisited." Croatica Chemica Acta 69, br. 4 (1996): 1275-1304. https://hrcak.srce.hr/135970
Harvard
Sunko, D.E. (1996). 'Secondary Deuterium Isotope Effects and Neighboring Group Participation Revisited', Croatica Chemica Acta, 69(4), str. 1275-1304. Preuzeto s: https://hrcak.srce.hr/135970 (Datum pristupa: 08.03.2021.)
Vancouver
Sunko DE. Secondary Deuterium Isotope Effects and Neighboring Group Participation Revisited. Croatica Chemica Acta [Internet]. 1996 [pristupljeno 08.03.2021.];69(4):1275-1304. Dostupno na: https://hrcak.srce.hr/135970
IEEE
D.E. Sunko, "Secondary Deuterium Isotope Effects and Neighboring Group Participation Revisited", Croatica Chemica Acta, vol.69, br. 4, str. 1275-1304, 1996. [Online]. Dostupno na: https://hrcak.srce.hr/135970. [Citirano: 08.03.2021.]

Sažetak
Studies on solvolytic reactions proceeding via neighboring group participation by means of secondary deuterium isotope effects are reviewed. The changes in magnitude of secondary KIEs are related to the degree of participation in the reaction transition state and these data are compared with other experimental evidence. Supporting information on the structure of carbocations is obtained by high level ab initio calculations. Isotope effect studies turned out to be among the most powerful tools available to chemists for elucidating the nature and structure of reaction transition states.
»For progress there is no cure« J. von Neumann, 1955

Hrčak ID: 135970

URI
https://hrcak.srce.hr/135970

Posjeta: 236 *