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Synthesis of Two Novel Tetranuclear Molybdenum(V) Complexes. Crystal Structure of Hexa-μ-propionato-dichlorodi-μ3-oxotetraoxotetramolybdenum(V)

Boris Kamenar ; Laboratory of General and Inorganic Chemistry, Faculty of Science, University of Zagreb, P.O.Box 153, 10000 Zagreb, Croatia
Branka Korpar-Čolig ; Laboratory of General and Inorganic Chemistry, Faculty of Science, University of Zagreb, P.O.Box 153, 10000 Zagreb, Croatia
Maja Penavić ; Laboratory of General and Inorganic Chemistry, Faculty of Science, University of Zagreb, P.O.Box 153, 10000 Zagreb, Croatia

Puni tekst: engleski, pdf (10 MB) str. 1377-1384 preuzimanja: 167* citiraj
APA 6th Edition
Kamenar, B., Korpar-Čolig, B. i Penavić, M. (1996). Synthesis of Two Novel Tetranuclear Molybdenum(V) Complexes. Crystal Structure of Hexa-μ-propionato-dichlorodi-μ3-oxotetraoxotetramolybdenum(V). Croatica Chemica Acta, 69 (4), 1377-1384. Preuzeto s https://hrcak.srce.hr/135977
MLA 8th Edition
Kamenar, Boris, et al. "Synthesis of Two Novel Tetranuclear Molybdenum(V) Complexes. Crystal Structure of Hexa-μ-propionato-dichlorodi-μ3-oxotetraoxotetramolybdenum(V)." Croatica Chemica Acta, vol. 69, br. 4, 1996, str. 1377-1384. https://hrcak.srce.hr/135977. Citirano 07.03.2021.
Chicago 17th Edition
Kamenar, Boris, Branka Korpar-Čolig i Maja Penavić. "Synthesis of Two Novel Tetranuclear Molybdenum(V) Complexes. Crystal Structure of Hexa-μ-propionato-dichlorodi-μ3-oxotetraoxotetramolybdenum(V)." Croatica Chemica Acta 69, br. 4 (1996): 1377-1384. https://hrcak.srce.hr/135977
Harvard
Kamenar, B., Korpar-Čolig, B., i Penavić, M. (1996). 'Synthesis of Two Novel Tetranuclear Molybdenum(V) Complexes. Crystal Structure of Hexa-μ-propionato-dichlorodi-μ3-oxotetraoxotetramolybdenum(V)', Croatica Chemica Acta, 69(4), str. 1377-1384. Preuzeto s: https://hrcak.srce.hr/135977 (Datum pristupa: 07.03.2021.)
Vancouver
Kamenar B, Korpar-Čolig B, Penavić M. Synthesis of Two Novel Tetranuclear Molybdenum(V) Complexes. Crystal Structure of Hexa-μ-propionato-dichlorodi-μ3-oxotetraoxotetramolybdenum(V). Croatica Chemica Acta [Internet]. 1996 [pristupljeno 07.03.2021.];69(4):1377-1384. Dostupno na: https://hrcak.srce.hr/135977
IEEE
B. Kamenar, B. Korpar-Čolig i M. Penavić, "Synthesis of Two Novel Tetranuclear Molybdenum(V) Complexes. Crystal Structure of Hexa-μ-propionato-dichlorodi-μ3-oxotetraoxotetramolybdenum(V)", Croatica Chemica Acta, vol.69, br. 4, str. 1377-1384, 1996. [Online]. Dostupno na: https://hrcak.srce.hr/135977. [Citirano: 07.03.2021.]

Sažetak
In the reaction of MoO2Cl2 and MoO22Br2 with propionic anhydride, new complexes of molybdenum(V), and Mo4O6Br2(OCOC2H5)6, respectively, have been prepared. The crystal structure of the former was determined from single crystal diffractometer data and refined to the final R value of 0.046. The complex crystallizes in the monoclinic space group P2\!n with cell dimensions a = 11.713(2) Å, b = 9.292(3) Å, c = 30.957(6) Å, f = 96.71(2)°, Z)caic = 1.963 g cm-3, Z = 4. The tetranuclear complex molecule contains four molybdenum atoms bridged through two oxo- oxygen atoms and six bidentate propionato-ligands. Two of the four molybdenum atoms form a Mo-Mo bond at 2.592(3) A.

Hrčak ID: 135977

URI
https://hrcak.srce.hr/135977

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