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Octahedral Cluster Compounds in the Tungsten Bromide Chemistry: MW6Br14 and 2W6Br14. The Crystal Structure of CdW6Br14

Saadìa Ihmaine ; Laboratoire de Chìmie du Solide et Inorganique Moléculaire, URA CNRS 1495, Université de Rennes I, Avenue du Général Leclerc, 35042 Rennes Cédex, France
Christiane Perrin ; Laboratoire de Chìmie du Solide et Inorganique Moléculaire, URA CNRS 1495, Université de Rennes I, Avenue du Général Leclerc, 35042 Rennes Cédex, France
Marcel Sergent ; Laboratoire de Chìmie du Solide et Inorganique Moléculaire, URA CNRS 1495, Université de Rennes I, Avenue du Général Leclerc, 35042 Rennes Cédex, France

Puni tekst: engleski, pdf (17 MB) str. 877-884 preuzimanja: 116* citiraj
APA 6th Edition
Ihmaine, S., Perrin, C. i Sergent, M. (1995). Octahedral Cluster Compounds in the Tungsten Bromide Chemistry: MW6Br14 and 2W6Br14. The Crystal Structure of CdW6Br14. Croatica Chemica Acta, 68 (4), 877-884. Preuzeto s https://hrcak.srce.hr/136699
MLA 8th Edition
Ihmaine, Saadìa, et al. "Octahedral Cluster Compounds in the Tungsten Bromide Chemistry: MW6Br14 and 2W6Br14. The Crystal Structure of CdW6Br14." Croatica Chemica Acta, vol. 68, br. 4, 1995, str. 877-884. https://hrcak.srce.hr/136699. Citirano 28.02.2021.
Chicago 17th Edition
Ihmaine, Saadìa, Christiane Perrin i Marcel Sergent. "Octahedral Cluster Compounds in the Tungsten Bromide Chemistry: MW6Br14 and 2W6Br14. The Crystal Structure of CdW6Br14." Croatica Chemica Acta 68, br. 4 (1995): 877-884. https://hrcak.srce.hr/136699
Harvard
Ihmaine, S., Perrin, C., i Sergent, M. (1995). 'Octahedral Cluster Compounds in the Tungsten Bromide Chemistry: MW6Br14 and 2W6Br14. The Crystal Structure of CdW6Br14', Croatica Chemica Acta, 68(4), str. 877-884. Preuzeto s: https://hrcak.srce.hr/136699 (Datum pristupa: 28.02.2021.)
Vancouver
Ihmaine S, Perrin C, Sergent M. Octahedral Cluster Compounds in the Tungsten Bromide Chemistry: MW6Br14 and 2W6Br14. The Crystal Structure of CdW6Br14. Croatica Chemica Acta [Internet]. 1995 [pristupljeno 28.02.2021.];68(4):877-884. Dostupno na: https://hrcak.srce.hr/136699
IEEE
S. Ihmaine, C. Perrin i M. Sergent, "Octahedral Cluster Compounds in the Tungsten Bromide Chemistry: MW6Br14 and 2W6Br14. The Crystal Structure of CdW6Br14", Croatica Chemica Acta, vol.68, br. 4, str. 877-884, 1995. [Online]. Dostupno na: https://hrcak.srce.hr/136699. [Citirano: 28.02.2021.]

Sažetak
The title compounds synthesized by solid state reaction crystallize in the cubic system (Pn3) and are based on isolated [(WgBrgbBrg3]2- units. For MIIWgBr14 the units are linked together by divalent cations lying at octahedral sites of apical bromines belonging to six adjacent units. In the case of M^WgBr^, the cohesion of the stacking is effected by pairs of monovalent counter cations located at two alternant triangular sites of apical bromines, each of them built of three adjacent units; these two triangular sites correspond to a split octahedral one occupied by the divalent cation in the structure of MIIWgBr14. The structure of CdW6Br14) refined from single crystal X- ray diffraction data, is detailed.

Hrčak ID: 136699

URI
https://hrcak.srce.hr/136699

Posjeta: 228 *