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Thermodynamics of the Cell: Cd(Hg)satd.|CdCl2(m)|AgCl|Ag in (10, 30 and 50 Mass per Cent) 2-Propanol-Water Mixtures

M. Višić ; Laboratory of Physical Chemistry, Faculty of Technology, University of Split, 58000 Split, Teslina 10, Croatia
I. Mekjavić ; Laboratory of Physical Chemistry, Faculty of Technology, University of Split, 58000 Split, Teslina 10, Croatia

Puni tekst: engleski, pdf (22 MB) str. 479-488 preuzimanja: 110* citiraj
APA 6th Edition
Višić, M. i Mekjavić, I. (1993). Thermodynamics of the Cell: Cd(Hg)satd.|CdCl2(m)|AgCl|Ag in (10, 30 and 50 Mass per Cent) 2-Propanol-Water Mixtures. Croatica Chemica Acta, 66 (3-4), 479-488. Preuzeto s https://hrcak.srce.hr/137049
MLA 8th Edition
Višić, M. i I. Mekjavić. "Thermodynamics of the Cell: Cd(Hg)satd.|CdCl2(m)|AgCl|Ag in (10, 30 and 50 Mass per Cent) 2-Propanol-Water Mixtures." Croatica Chemica Acta, vol. 66, br. 3-4, 1993, str. 479-488. https://hrcak.srce.hr/137049. Citirano 28.02.2021.
Chicago 17th Edition
Višić, M. i I. Mekjavić. "Thermodynamics of the Cell: Cd(Hg)satd.|CdCl2(m)|AgCl|Ag in (10, 30 and 50 Mass per Cent) 2-Propanol-Water Mixtures." Croatica Chemica Acta 66, br. 3-4 (1993): 479-488. https://hrcak.srce.hr/137049
Harvard
Višić, M., i Mekjavić, I. (1993). 'Thermodynamics of the Cell: Cd(Hg)satd.|CdCl2(m)|AgCl|Ag in (10, 30 and 50 Mass per Cent) 2-Propanol-Water Mixtures', Croatica Chemica Acta, 66(3-4), str. 479-488. Preuzeto s: https://hrcak.srce.hr/137049 (Datum pristupa: 28.02.2021.)
Vancouver
Višić M, Mekjavić I. Thermodynamics of the Cell: Cd(Hg)satd.|CdCl2(m)|AgCl|Ag in (10, 30 and 50 Mass per Cent) 2-Propanol-Water Mixtures. Croatica Chemica Acta [Internet]. 1993 [pristupljeno 28.02.2021.];66(3-4):479-488. Dostupno na: https://hrcak.srce.hr/137049
IEEE
M. Višić i I. Mekjavić, "Thermodynamics of the Cell: Cd(Hg)satd.|CdCl2(m)|AgCl|Ag in (10, 30 and 50 Mass per Cent) 2-Propanol-Water Mixtures", Croatica Chemica Acta, vol.66, br. 3-4, str. 479-488, 1993. [Online]. Dostupno na: https://hrcak.srce.hr/137049. [Citirano: 28.02.2021.]

Sažetak
The e.m.f. of the cell: Cd(Hg)satd. | CdC^m) |AgCl|Ag in 2-propanol- water mixtures (containing 10, 30 and 50 mass per cent 2-propanol) was measured in the temperature range 293.15 K • • • 313.15 K at 5 K intervals and in the range of molality of CdCl2 0.002 < m/mol kg-1 < 0.02. The measured values were processed in order to obtain the standard e.m.f. of the cell for each temperature by (a) using the literature values for the stability constants of all Cd chlorido complexes and (b) assuming that only the CdCl+ complex was present in the solution. The values obtained by both methods were compared and discussed. The values obtained by the first method were used to calculate the standard thermodynamic quantities for the cell reaction and the mean activity coefficients of CdCl2. The standard thermodynamic quantities for CdCl2 transfer from water to the investigated 2-propanol- water mixtures were also calculated. These values were compared with those obtained for the transfer of electrolytes HC1, HBr and HI to the same mixtures.

Hrčak ID: 137049

URI
https://hrcak.srce.hr/137049

Posjeta: 225 *