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Ion-Association Reaction of H+ and Br- in (90 and 95 Mass per Cent) 1-Butanol-Water, and (90 and 95 Mass per Cent) 2-Methyl-2-Propanol-Water Mixtures

I. Tominić ; Laboratory of Physical Chemistry, Faculty of Technology, University of Split, 58000 Split, Teslina 10, Croatia, Yugoslavia
I. Mekjavić ; Laboratory of Physical Chemistry, Faculty of Technology, University of Split, 58000 Split, Teslina 10, Croatia, Yugoslavia

Puni tekst: engleski, pdf (11 MB) str. 189-197 preuzimanja: 110* citiraj
APA 6th Edition
Tominić, I. i Mekjavić, I. (1991). Ion-Association Reaction of H+ and Br- in (90 and 95 Mass per Cent) 1-Butanol-Water, and (90 and 95 Mass per Cent) 2-Methyl-2-Propanol-Water Mixtures. Croatica Chemica Acta, 64 (2), 189-197. Preuzeto s https://hrcak.srce.hr/137324
MLA 8th Edition
Tominić, I. i I. Mekjavić. "Ion-Association Reaction of H+ and Br- in (90 and 95 Mass per Cent) 1-Butanol-Water, and (90 and 95 Mass per Cent) 2-Methyl-2-Propanol-Water Mixtures." Croatica Chemica Acta, vol. 64, br. 2, 1991, str. 189-197. https://hrcak.srce.hr/137324. Citirano 19.09.2020.
Chicago 17th Edition
Tominić, I. i I. Mekjavić. "Ion-Association Reaction of H+ and Br- in (90 and 95 Mass per Cent) 1-Butanol-Water, and (90 and 95 Mass per Cent) 2-Methyl-2-Propanol-Water Mixtures." Croatica Chemica Acta 64, br. 2 (1991): 189-197. https://hrcak.srce.hr/137324
Harvard
Tominić, I., i Mekjavić, I. (1991). 'Ion-Association Reaction of H+ and Br- in (90 and 95 Mass per Cent) 1-Butanol-Water, and (90 and 95 Mass per Cent) 2-Methyl-2-Propanol-Water Mixtures', Croatica Chemica Acta, 64(2), str. 189-197. Preuzeto s: https://hrcak.srce.hr/137324 (Datum pristupa: 19.09.2020.)
Vancouver
Tominić I, Mekjavić I. Ion-Association Reaction of H+ and Br- in (90 and 95 Mass per Cent) 1-Butanol-Water, and (90 and 95 Mass per Cent) 2-Methyl-2-Propanol-Water Mixtures. Croatica Chemica Acta [Internet]. 1991 [pristupljeno 19.09.2020.];64(2):189-197. Dostupno na: https://hrcak.srce.hr/137324
IEEE
I. Tominić i I. Mekjavić, "Ion-Association Reaction of H+ and Br- in (90 and 95 Mass per Cent) 1-Butanol-Water, and (90 and 95 Mass per Cent) 2-Methyl-2-Propanol-Water Mixtures", Croatica Chemica Acta, vol.64, br. 2, str. 189-197, 1991. [Online]. Dostupno na: https://hrcak.srce.hr/137324. [Citirano: 19.09.2020.]

Sažetak
The molar conductivities of HBr in the 90 and 95 mass per cent 2-met- hyl-2-propanol-water and 1-butanol-water mixtures, respectively, were measured in the temperature range from 288.15 to 308. 15 K at 5 K intervals.
By means of the conductance equations after Fuoss-Hsia and Lee-Wheaton the limiting molar conductivity (Ao), association constant (KA) and the radius of the ion pair (R) were obtained from these data. The data for R differ considerably, so that KA and A0 were also calculated with the same equations under the condition that R = q (q is the Bjerrum critical distance). The influence of the dielectric constant on KA and Ao was established and discussed and comparison was made with analogous literature data for 2-butanol-water and tert. butanol-water mixtures. From the data for KA at different temperatures (under the conditionR = q) the standard thermodynamic quantities for association reaction of H+ and Br" were determined.

Hrčak ID: 137324

URI
https://hrcak.srce.hr/137324

Posjeta: 191 *