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https://doi.org/10.5562/cca2687

Glucosinolate Profile of Croatian Stenoendemic Plant Fibigia triquetra (DC.) Boiss. ex Prantl.

Ivica Blažević   ORCID icon orcid.org/0000-0002-0715-3216 ; University of Split, Faculty of Chemistry and Technology, Department of Organic Chemistry, Teslina 10/V, 21000 Split, Croatia
Gina Rosalinda De Nicola ; Consiglio per la ricerca in agricoltura e l’analisi dell’economia agraria - Centro di ricerca per le colture industriali (CREA-CIN), Via di Corticella 133, I-40128 Bologna, Italy
Sabine Montaut   ORCID icon orcid.org/0000-0002-8223-4809 ; Department of Chemistry and Biochemistry, Biomolecular Sciences Programme, Laurentian University, 935 Ramsey Lake Road, Sudbury, ONP3E 2C6, Canada
Patrick Rollin ; Université d’Orléans et CNRS, ICOA, UMR 7311, BP 6759, F-45067 Orléans, France
Mirko Ruščić ; University of Split, Faculty of Sciences, Department of Biology, Teslina 12/V, 21000 Split, Croatia

Puni tekst: engleski, pdf (711 KB) str. 307-314 preuzimanja: 649* citiraj
APA 6th Edition
Blažević, I., De Nicola, G.R., Montaut, S., Rollin, P. i Ruščić, M. (2015). Glucosinolate Profile of Croatian Stenoendemic Plant Fibigia triquetra (DC.) Boiss. ex Prantl.. Croatica Chemica Acta, 88 (3), 307-314. https://doi.org/10.5562/cca2687
MLA 8th Edition
Blažević, Ivica, et al. "Glucosinolate Profile of Croatian Stenoendemic Plant Fibigia triquetra (DC.) Boiss. ex Prantl.." Croatica Chemica Acta, vol. 88, br. 3, 2015, str. 307-314. https://doi.org/10.5562/cca2687. Citirano 07.04.2020.
Chicago 17th Edition
Blažević, Ivica, Gina Rosalinda De Nicola, Sabine Montaut, Patrick Rollin i Mirko Ruščić. "Glucosinolate Profile of Croatian Stenoendemic Plant Fibigia triquetra (DC.) Boiss. ex Prantl.." Croatica Chemica Acta 88, br. 3 (2015): 307-314. https://doi.org/10.5562/cca2687
Harvard
Blažević, I., et al. (2015). 'Glucosinolate Profile of Croatian Stenoendemic Plant Fibigia triquetra (DC.) Boiss. ex Prantl.', Croatica Chemica Acta, 88(3), str. 307-314. https://doi.org/10.5562/cca2687
Vancouver
Blažević I, De Nicola GR, Montaut S, Rollin P, Ruščić M. Glucosinolate Profile of Croatian Stenoendemic Plant Fibigia triquetra (DC.) Boiss. ex Prantl.. Croatica Chemica Acta [Internet]. 2015 [pristupljeno 07.04.2020.];88(3):307-314. https://doi.org/10.5562/cca2687
IEEE
I. Blažević, G.R. De Nicola, S. Montaut, P. Rollin i M. Ruščić, "Glucosinolate Profile of Croatian Stenoendemic Plant Fibigia triquetra (DC.) Boiss. ex Prantl.", Croatica Chemica Acta, vol.88, br. 3, str. 307-314, 2015. [Online]. https://doi.org/10.5562/cca2687

Sažetak
As part of our ongoing investigation of the stenoendemic plants belonging to the Brassicaceae family, we report on the chemistry of Fibigia triquetra (DC.) Boiss. ex Prantl for the first time. Different plant parts (flower, leaf, stem, and seed) of F. triquetra were characterized and quantified for glucosinolates (GLs) according to the ISO 9167-1 EU official method based on the HPLC analysis of desulfo-GLs. A taxonomic screening showed that F. triquetra contained relatively high levels of C-4 GLs, namely but-3-enyl GL (gluconapin, 1a), 4-methylsulfanylbutyl GL (glucoerucin, 3a), and 4-methylsulfinylbutyl GL (glucoraphanin, 5a). GC-MS analysis of the volatile fractions obtained after enzyme hydrolysis and/or HPLC-ESI-MS of intact GLs confirmed the GL profile. Four minor GLs, namely isopropyl GL (glucoputranjivin, 6a), sec-butyl GL (glucocochlearin, 7a), pent-4-enyl GL (glucobrassicanapin, 2a), and 5-methylsulfanylpentyl GL (glucoberteroin, 4a) were also identified and quantified while 4-methylpentyl GL, 5-methylhexyl GL, and n-heptyl GL, were tentatively identified by GC-MS of their degradation products. Based on the major, as well as the minor GLs, this study shows differences in chemotaxonomy between F. triquetra and the related Degenia velebitica (Degen) Hayek as well as other investigated species of the genus Fibigia.

Ključne riječi
Fibigia triquetra; Brassicaceae; glucosinolates; desulfo-glucosinolates; isothiocyanates

Hrčak ID: 150536

URI
https://hrcak.srce.hr/150536

Posjeta: 900 *