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Absorptiometric determination of organophosphorus insecticides

K. Weber ; Institut za medicinska istraživanja i medicinu rada JAZU, Zagreb
Jelka Matković ; Institut za medicinska istraživanja i medicinu rada JAZU, Zagreb
Ljerka Palla ; Institut za medicinska istraživanja i medicinu rada JAZU, Zagreb

Puni tekst: hrvatski, pdf (11 MB) str. 477-491 preuzimanja: 131* citiraj
APA 6th Edition
Weber, K., Matković, J. i Palla, Lj. (1968). Apsorpciometrijsko određivanje organofosfornih insekticida. Arhiv za higijenu rada i toksikologiju, 19 (4), 477-491. Preuzeto s https://hrcak.srce.hr/175997
MLA 8th Edition
Weber, K., et al. "Apsorpciometrijsko određivanje organofosfornih insekticida." Arhiv za higijenu rada i toksikologiju, vol. 19, br. 4, 1968, str. 477-491. https://hrcak.srce.hr/175997. Citirano 27.02.2021.
Chicago 17th Edition
Weber, K., Jelka Matković i Ljerka Palla. "Apsorpciometrijsko određivanje organofosfornih insekticida." Arhiv za higijenu rada i toksikologiju 19, br. 4 (1968): 477-491. https://hrcak.srce.hr/175997
Harvard
Weber, K., Matković, J., i Palla, Lj. (1968). 'Apsorpciometrijsko određivanje organofosfornih insekticida', Arhiv za higijenu rada i toksikologiju, 19(4), str. 477-491. Preuzeto s: https://hrcak.srce.hr/175997 (Datum pristupa: 27.02.2021.)
Vancouver
Weber K, Matković J, Palla Lj. Apsorpciometrijsko određivanje organofosfornih insekticida. Arh Hig Rada Toksikol. [Internet]. 1968 [pristupljeno 27.02.2021.];19(4):477-491. Dostupno na: https://hrcak.srce.hr/175997
IEEE
K. Weber, J. Matković i Lj. Palla, "Apsorpciometrijsko određivanje organofosfornih insekticida", Arhiv za higijenu rada i toksikologiju, vol.19, br. 4, str. 477-491, 1968. [Online]. Dostupno na: https://hrcak.srce.hr/175997. [Citirano: 27.02.2021.]

Sažetak
The oxidation reaction of o-dianisidine and benzidine has been applied for quantitative determination of organophosphorus insecticides. Extinction of reaction solutions determined at 450 nm in a 1 cm cell was taken as a measure of insecticide concentration. Extinctions were determined by absorptiometric photoelectric measurements. Optimum conditions for the method have been found. In experiments were used various organophosphorus insecticides which are widely applied in practice. Constants of calibration lines for such analytical measurements are given. Results of measurements have been statistically treated and standard errors calculated. The insecticide Dipterex can be determined by this method at as low concentrations as 1.10-4 %, what corresponds to 0.01 mg in the reaction mixture of 10 ml. For a number of other insecticides (ortho-dibrorno, Dimecron, Parathion, Neocide and Nancor) this limit concentration is approximately 10 times higher, while in some cases (Phencapton) it is even 100-fold. Advantage of this absorptiometric method Iies in its applicability to organophosphorus poisons (Parathion) whose quantitative analysis is not possible by the methods of chemiluminescence and fluorescence. The absorptiometric method for determination of organophosphorus insecticides yields good results also in determinanion of these poisons in (dry) foods. In wet foods the stability of organophosphorus compounds is considerably reduced due to hydrolysis catalysed by some food components. For determination of insecticides in food construction of special calibration lines is required.

Hrčak ID: 175997

URI
https://hrcak.srce.hr/175997

[hrvatski]

Posjeta: 297 *