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Progress in the Understanding of the Structure of the Metal Electrode/Solution Interface. Evolution of the Concept of Hydrophilicity

Sergio Trasatti ; Department of Physical Chemistry and Electrochemistry, University of Milan, Via Venezian 21, 20133 Milan, Italy

Puni tekst: engleski, pdf (6 MB) str. 357-370 preuzimanja: 112* citiraj
APA 6th Edition
Trasatti, S. (1987). Progress in the Understanding of the Structure of the Metal Electrode/Solution Interface. Evolution of the Concept of Hydrophilicity. Croatica Chemica Acta, 60 (3), 357-370. Preuzeto s https://hrcak.srce.hr/176365
MLA 8th Edition
Trasatti, Sergio. "Progress in the Understanding of the Structure of the Metal Electrode/Solution Interface. Evolution of the Concept of Hydrophilicity." Croatica Chemica Acta, vol. 60, br. 3, 1987, str. 357-370. https://hrcak.srce.hr/176365. Citirano 07.03.2021.
Chicago 17th Edition
Trasatti, Sergio. "Progress in the Understanding of the Structure of the Metal Electrode/Solution Interface. Evolution of the Concept of Hydrophilicity." Croatica Chemica Acta 60, br. 3 (1987): 357-370. https://hrcak.srce.hr/176365
Harvard
Trasatti, S. (1987). 'Progress in the Understanding of the Structure of the Metal Electrode/Solution Interface. Evolution of the Concept of Hydrophilicity', Croatica Chemica Acta, 60(3), str. 357-370. Preuzeto s: https://hrcak.srce.hr/176365 (Datum pristupa: 07.03.2021.)
Vancouver
Trasatti S. Progress in the Understanding of the Structure of the Metal Electrode/Solution Interface. Evolution of the Concept of Hydrophilicity. Croatica Chemica Acta [Internet]. 1987 [pristupljeno 07.03.2021.];60(3):357-370. Dostupno na: https://hrcak.srce.hr/176365
IEEE
S. Trasatti, "Progress in the Understanding of the Structure of the Metal Electrode/Solution Interface. Evolution of the Concept of Hydrophilicity", Croatica Chemica Acta, vol.60, br. 3, str. 357-370, 1987. [Online]. Dostupno na: https://hrcak.srce.hr/176365. [Citirano: 07.03.2021.]

Sažetak
The metal-water interaction strength (»hydrophilicity«) plays
a major role in determining both the structure of the interfacial
region and the energetics of adsorption phenomena. A »hydrophilicity
« scale can be established on the basis of a phenomenological approach for a series of sp-metals. It is shown that recent results for sd-metals (Cu, Ag, Au) cannot be organized in the same picture. This has lead to a reconsideration of the factors governing the behaviour of an electrode interface. The role of the surface electron gas, thus far underestimated, should be revaluated. This is what »physical models« emphasize as opposite to »molecular models« for which the response of the interface is simply that of a monolayer of solvent molecules. It is stressed that these conceptual developments do not clash with conclusions of the phenomenological approach based on the correlation of a few experimental parameters with some physicochemical properties of metals.

Hrčak ID: 176365

URI
https://hrcak.srce.hr/176365

Posjeta: 205 *