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Kinetics of N-Alkyl Side Chain Oxidations. Oxidation of N,N-Dimethylaniline by Alkaline Hexacyanoferrate(III)

Gopa Dasgupta ; Department of Chemistry North-Eastern Hill University, Shillong 793003, India
Mahendra K. Mahanti ; Department of Chemistry North-Eastern Hill University, Shillong 793003, India

Puni tekst: engleski, pdf (2 MB) str. 407-411 preuzimanja: 86* citiraj
APA 6th Edition
Dasgupta, G. i Mahanti, M.K. (1986). Kinetics of N-Alkyl Side Chain Oxidations. Oxidation of N,N-Dimethylaniline by Alkaline Hexacyanoferrate(III). Croatica Chemica Acta, 59 (2), 407-411. Preuzeto s https://hrcak.srce.hr/177367
MLA 8th Edition
Dasgupta, Gopa i Mahendra K. Mahanti. "Kinetics of N-Alkyl Side Chain Oxidations. Oxidation of N,N-Dimethylaniline by Alkaline Hexacyanoferrate(III)." Croatica Chemica Acta, vol. 59, br. 2, 1986, str. 407-411. https://hrcak.srce.hr/177367. Citirano 26.02.2021.
Chicago 17th Edition
Dasgupta, Gopa i Mahendra K. Mahanti. "Kinetics of N-Alkyl Side Chain Oxidations. Oxidation of N,N-Dimethylaniline by Alkaline Hexacyanoferrate(III)." Croatica Chemica Acta 59, br. 2 (1986): 407-411. https://hrcak.srce.hr/177367
Harvard
Dasgupta, G., i Mahanti, M.K. (1986). 'Kinetics of N-Alkyl Side Chain Oxidations. Oxidation of N,N-Dimethylaniline by Alkaline Hexacyanoferrate(III)', Croatica Chemica Acta, 59(2), str. 407-411. Preuzeto s: https://hrcak.srce.hr/177367 (Datum pristupa: 26.02.2021.)
Vancouver
Dasgupta G, Mahanti MK. Kinetics of N-Alkyl Side Chain Oxidations. Oxidation of N,N-Dimethylaniline by Alkaline Hexacyanoferrate(III). Croatica Chemica Acta [Internet]. 1986 [pristupljeno 26.02.2021.];59(2):407-411. Dostupno na: https://hrcak.srce.hr/177367
IEEE
G. Dasgupta i M.K. Mahanti, "Kinetics of N-Alkyl Side Chain Oxidations. Oxidation of N,N-Dimethylaniline by Alkaline Hexacyanoferrate(III)", Croatica Chemica Acta, vol.59, br. 2, str. 407-411, 1986. [Online]. Dostupno na: https://hrcak.srce.hr/177367. [Citirano: 26.02.2021.]

Sažetak
The oxidation of N,N-dimethylaniline by alkaline hexacyanoferrate(
III), at constant ionic strength, gave N-methylformanilide. The rate of the reaction was dependent on the first powers of the' concentrations of substrate and oxidant, but was independent of the concentration of alkali in the range studied (0.01 M to 0.10 M). The mechanistic pathway involved an electron abstraction from the amine, giving a radical intermediate which was detected by ESR spectroscopy as a three-line spectrum with a peak height
of 1 : 2 : 1.

Hrčak ID: 177367

URI
https://hrcak.srce.hr/177367

Posjeta: 161 *