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https://doi.org/10.5562/cca3079

Immobilised Co(II) Homodinuclear Coordinative Compound with Terephthalate and o-phenanthroline as Ligands: Synthesis, Crystal Structure and Applications

Catalin Blegescu ; "Al.I. Cuza" University of Iasi, Faculty of Chemistry, Carol I, nr. 11 Bld., Iasi, 700506, Romania
Dumitru Ganju ; "Al.I. Cuza" University of Iasi, Faculty of Chemistry, Carol I, nr. 11 Bld., Iasi, 700506, Romania
Sergiu Shova ; "Petru Poni" Institute of Macromolecular Chemistry, Aleea Gr. Ghica Voda 41 A, Iasi, 700487, Romania
Doina Humelnicu ; "Al.I. Cuza" University of Iasi, Faculty of Chemistry, Carol I, nr. 11 Bld., Iasi, 700506, Romania

Puni tekst: engleski, pdf (2 MB) str. 59-66 preuzimanja: 584* citiraj
APA 6th Edition
Blegescu, C., Ganju, D., Shova, S. i Humelnicu, D. (2017). Immobilised Co(II) Homodinuclear Coordinative Compound with Terephthalate and o-phenanthroline as Ligands: Synthesis, Crystal Structure and Applications. Croatica Chemica Acta, 90 (1), 59-66. https://doi.org/10.5562/cca3079
MLA 8th Edition
Blegescu, Catalin, et al. "Immobilised Co(II) Homodinuclear Coordinative Compound with Terephthalate and o-phenanthroline as Ligands: Synthesis, Crystal Structure and Applications." Croatica Chemica Acta, vol. 90, br. 1, 2017, str. 59-66. https://doi.org/10.5562/cca3079. Citirano 25.02.2021.
Chicago 17th Edition
Blegescu, Catalin, Dumitru Ganju, Sergiu Shova i Doina Humelnicu. "Immobilised Co(II) Homodinuclear Coordinative Compound with Terephthalate and o-phenanthroline as Ligands: Synthesis, Crystal Structure and Applications." Croatica Chemica Acta 90, br. 1 (2017): 59-66. https://doi.org/10.5562/cca3079
Harvard
Blegescu, C., et al. (2017). 'Immobilised Co(II) Homodinuclear Coordinative Compound with Terephthalate and o-phenanthroline as Ligands: Synthesis, Crystal Structure and Applications', Croatica Chemica Acta, 90(1), str. 59-66. https://doi.org/10.5562/cca3079
Vancouver
Blegescu C, Ganju D, Shova S, Humelnicu D. Immobilised Co(II) Homodinuclear Coordinative Compound with Terephthalate and o-phenanthroline as Ligands: Synthesis, Crystal Structure and Applications. Croatica Chemica Acta [Internet]. 2017 [pristupljeno 25.02.2021.];90(1):59-66. https://doi.org/10.5562/cca3079
IEEE
C. Blegescu, D. Ganju, S. Shova i D. Humelnicu, "Immobilised Co(II) Homodinuclear Coordinative Compound with Terephthalate and o-phenanthroline as Ligands: Synthesis, Crystal Structure and Applications", Croatica Chemica Acta, vol.90, br. 1, str. 59-66, 2017. [Online]. https://doi.org/10.5562/cca3079

Sažetak
Homodinuclear coordinative compound of Co(II) with terephthalate bridge and o-phenanthroline has been synthesized and characterized by elemental analysis, FT-IR spectroscopy, thermal analysis. The crystal structure was determined by single crystal X–ray diffraction technique. The coordinative compound was immobilized into functionalized silica with thiol groups and tested for its catalytic activity towards styrene oxidation in the presence of H2O2. A conversion of 89.75 % and selectivity of 85.4 % for benzaldehyde formation was obtained.

Creative Commons License This work is licensed under a Creative Commons Attribution 4.0 International License.

Ključne riječi
terephthalate bridge; catalytic activity; styrene oxide; functionalised silica; o-phenanthroline

Hrčak ID: 182674

URI
https://hrcak.srce.hr/182674

Posjeta: 835 *