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Mercuration of Some Aliphatic Aldehydes. The Crystal Structure of 2,2-Bis(chloromercuri)butyraldehyde

Branka Korpar-Čolig ; Laboratory of General and Inorg11nic Chemistry, Faculty of Science, University of Zagreb, P . 0 . Box 153, 41001 Zagreb, Yugoslavia
Zora Popović ; Laboratory of General and Inorg11nic Chemistry, Faculty of Science, University of Zagreb, P . 0 . Box 153, 41001 Zagreb, Yugoslavia
Milan Sikirica ; Laboratory of General and Inorg11nic Chemistry, Faculty of Science, University of Zagreb, P . 0 . Box 153, 41001 Zagreb, Yugoslavia

Puni tekst: engleski, pdf (7 MB) str. 689-694 preuzimanja: 55* citiraj
APA 6th Edition
Korpar-Čolig, B., Popović, Z. i Sikirica, M. (1984). Mercuration of Some Aliphatic Aldehydes. The Crystal Structure of 2,2-Bis(chloromercuri)butyraldehyde. Croatica Chemica Acta, 57 (4), 689-694. Preuzeto s https://hrcak.srce.hr/194139
MLA 8th Edition
Korpar-Čolig, Branka, et al. "Mercuration of Some Aliphatic Aldehydes. The Crystal Structure of 2,2-Bis(chloromercuri)butyraldehyde." Croatica Chemica Acta, vol. 57, br. 4, 1984, str. 689-694. https://hrcak.srce.hr/194139. Citirano 31.03.2020.
Chicago 17th Edition
Korpar-Čolig, Branka, Zora Popović i Milan Sikirica. "Mercuration of Some Aliphatic Aldehydes. The Crystal Structure of 2,2-Bis(chloromercuri)butyraldehyde." Croatica Chemica Acta 57, br. 4 (1984): 689-694. https://hrcak.srce.hr/194139
Harvard
Korpar-Čolig, B., Popović, Z., i Sikirica, M. (1984). 'Mercuration of Some Aliphatic Aldehydes. The Crystal Structure of 2,2-Bis(chloromercuri)butyraldehyde', Croatica Chemica Acta, 57(4), str. 689-694. Preuzeto s: https://hrcak.srce.hr/194139 (Datum pristupa: 31.03.2020.)
Vancouver
Korpar-Čolig B, Popović Z, Sikirica M. Mercuration of Some Aliphatic Aldehydes. The Crystal Structure of 2,2-Bis(chloromercuri)butyraldehyde. Croatica Chemica Acta [Internet]. 1984 [pristupljeno 31.03.2020.];57(4):689-694. Dostupno na: https://hrcak.srce.hr/194139
IEEE
B. Korpar-Čolig, Z. Popović i M. Sikirica, "Mercuration of Some Aliphatic Aldehydes. The Crystal Structure of 2,2-Bis(chloromercuri)butyraldehyde", Croatica Chemica Acta, vol.57, br. 4, str. 689-694, 1984. [Online]. Dostupno na: https://hrcak.srce.hr/194139. [Citirano: 31.03.2020.]

Sažetak
Tris ( chloromercuri)acetaldehyde (1), 2,2-bis( chloromercuri)propionaldehyde
(II) and 2,2-bis(chloromercuri)butyraldehyde (III)
were obtained by mercuration of the corresponding aldehyde in an
aqueous mercury(II) chloride solution containing sodium acetate.
The mercurated aldehydes (II) and (III) are described for the first
time. The crystal structure of (III) was determined by means of
Patterson and Fourier syntheses based on threedimensional X-ray
diffractometer intensity data and refined by the full-matrix least-
squares method to an R value of 0.049. Crystals are orthorhombic,
space group Pna21 with z = 4 formula units in the unit cell of the
dimensions : a= 1114.6(6), b = 1121.3(5), c = 657.3(3) pm, Dots= 4.51and Deale = 4.38 Mg m-3• The structure consists of discrete moleculesof 2,2-bis(chloromercuri)butyraldehyde. The Hg-C bond lengthsare 216(2) and 209(2) pm. The Hg-C-Hg bond angle is 103(1) 0
and the C-Hg-Cl bond angles are 173(2)0 and 172(2)0
, respectively.

Hrčak ID: 194139

URI
https://hrcak.srce.hr/194139

Posjeta: 89 *