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Solvolysis Reactions of tert-Butyl Chloride and Methyl Tosylate in Trimethoxyborane Methanol Mixtures

I. Szele ; aboratory of Organic Chemistry and Biochemistry, Faculty of Science, University of Zagreb, 41000 Zagreb, Yugoslavia
B. Mulac ; aboratory of Organic Chemistry and Biochemistry, Faculty of Science, University of Zagreb, 41000 Zagreb, Yugoslavia

Puni tekst: engleski, pdf (4 MB) str. 47-56 preuzimanja: 369* citiraj
APA 6th Edition
Szele, I. i Mulac, B. (1977). Solvolysis Reactions of tert-Butyl Chloride and Methyl Tosylate in Trimethoxyborane Methanol Mixtures. Croatica Chemica Acta, 49 (1), 47-56. Preuzeto s https://hrcak.srce.hr/196411
MLA 8th Edition
Szele, I. i B. Mulac. "Solvolysis Reactions of tert-Butyl Chloride and Methyl Tosylate in Trimethoxyborane Methanol Mixtures." Croatica Chemica Acta, vol. 49, br. 1, 1977, str. 47-56. https://hrcak.srce.hr/196411. Citirano 02.03.2021.
Chicago 17th Edition
Szele, I. i B. Mulac. "Solvolysis Reactions of tert-Butyl Chloride and Methyl Tosylate in Trimethoxyborane Methanol Mixtures." Croatica Chemica Acta 49, br. 1 (1977): 47-56. https://hrcak.srce.hr/196411
Harvard
Szele, I., i Mulac, B. (1977). 'Solvolysis Reactions of tert-Butyl Chloride and Methyl Tosylate in Trimethoxyborane Methanol Mixtures', Croatica Chemica Acta, 49(1), str. 47-56. Preuzeto s: https://hrcak.srce.hr/196411 (Datum pristupa: 02.03.2021.)
Vancouver
Szele I, Mulac B. Solvolysis Reactions of tert-Butyl Chloride and Methyl Tosylate in Trimethoxyborane Methanol Mixtures. Croatica Chemica Acta [Internet]. 1977 [pristupljeno 02.03.2021.];49(1):47-56. Dostupno na: https://hrcak.srce.hr/196411
IEEE
I. Szele i B. Mulac, "Solvolysis Reactions of tert-Butyl Chloride and Methyl Tosylate in Trimethoxyborane Methanol Mixtures", Croatica Chemica Acta, vol.49, br. 1, str. 47-56, 1977. [Online]. Dostupno na: https://hrcak.srce.hr/196411. [Citirano: 02.03.2021.]

Sažetak
The solvolysis rates of t-butyl chloride and methyl tosyla.te
were measured in various trimethoxyborane - methanol mixtures.
The ionizing power and the nucleophilicity for the respective
solvent mJxtures were determirrled, and the suitability of this new
solvent system for the study of solvolytic reactions is discussed.
At elevated temperatures a reaction of hydrogen chloride, liberated
in the solvolysis of t~butyl chloride, with the solvent was observed,
and the r esults seem to indicate that methyl chloride is the reaction
product.

Hrčak ID: 196411

URI
https://hrcak.srce.hr/196411

Posjeta: 413 *