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Preliminary communication

Kinetic Study of the Substitution of Pyridine by Cyanide in the bis(pyridine)cobalt(IIl)hematoporphyrin-IX: Distinguishing between the Id and D Mechanism

M. Biruš ; Department of Chemistry, Faculty of Pharmacy and Biochemistry, University of Zagreb, Zagreb, Croatia, Yugoslavia
M. Pribanić ; Department of Chemistry, Faculty of Pharmacy and Biochemistry, University of Zagreb, Zagreb, Croatia, Yugoslavia

Fulltext: english, pdf (1 MB) pages 65-68 downloads: 59* cite
APA 6th Edition
Biruš, M. & Pribanić, M. (1977). Kinetic Study of the Substitution of Pyridine by Cyanide in the bis(pyridine)cobalt(IIl)hematoporphyrin-IX: Distinguishing between the Id and D Mechanism. Croatica Chemica Acta, 49 (1), 65-68. Retrieved from https://hrcak.srce.hr/196413
MLA 8th Edition
Biruš, M. and M. Pribanić. "Kinetic Study of the Substitution of Pyridine by Cyanide in the bis(pyridine)cobalt(IIl)hematoporphyrin-IX: Distinguishing between the Id and D Mechanism." Croatica Chemica Acta, vol. 49, no. 1, 1977, pp. 65-68. https://hrcak.srce.hr/196413. Accessed 22 Apr. 2021.
Chicago 17th Edition
Biruš, M. and M. Pribanić. "Kinetic Study of the Substitution of Pyridine by Cyanide in the bis(pyridine)cobalt(IIl)hematoporphyrin-IX: Distinguishing between the Id and D Mechanism." Croatica Chemica Acta 49, no. 1 (1977): 65-68. https://hrcak.srce.hr/196413
Harvard
Biruš, M., and Pribanić, M. (1977). 'Kinetic Study of the Substitution of Pyridine by Cyanide in the bis(pyridine)cobalt(IIl)hematoporphyrin-IX: Distinguishing between the Id and D Mechanism', Croatica Chemica Acta, 49(1), pp. 65-68. Available at: https://hrcak.srce.hr/196413 (Accessed 22 April 2021)
Vancouver
Biruš M, Pribanić M. Kinetic Study of the Substitution of Pyridine by Cyanide in the bis(pyridine)cobalt(IIl)hematoporphyrin-IX: Distinguishing between the Id and D Mechanism. Croatica Chemica Acta [Internet]. 1977 [cited 2021 April 22];49(1):65-68. Available from: https://hrcak.srce.hr/196413
IEEE
M. Biruš and M. Pribanić, "Kinetic Study of the Substitution of Pyridine by Cyanide in the bis(pyridine)cobalt(IIl)hematoporphyrin-IX: Distinguishing between the Id and D Mechanism", Croatica Chemica Acta, vol.49, no. 1, pp. 65-68, 1977. [Online]. Available: https://hrcak.srce.hr/196413. [Accessed: 22 April 2021]

Abstracts
A kinetic study of the reaction between the cyanide ion and the bis(pyridine)cobalt(III)hematoporphyrin-IX complex to give
(CN)2cobalt(lll)hematoporphyrin-IX has shown that the axial
ligand substitution occurs by a purely dissociative (D but not la)
mechanism in chloroform involving predissociation to a ' five-co-
ordinate (pyridine)cobalt(lll)hematoporphyrin-IX complex.

Hrčak ID: 196413

URI
https://hrcak.srce.hr/196413

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