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Original scientific paper

Reaction of Aryldiazonium Chlorides with 1,3,5-Triketones. An Evidence for the Azohydrazone Conversion

D. Škare ; Military Academy for Technical Sciences, 41000 Zagreb
M. Laćan ; Laboratory of Organic Chemistry and Technology, Biochemistry Department, Faculty of Technology, University of Zagreb, 41000 Zagreb
Z. Meić ; Institute »Rugjer Boskovic«, 41000 Zagreb, Croatia, Yugoslavia

Fulltext: english, pdf (7 MB) pages 135-143 downloads: 45* cite
APA 6th Edition
Škare, D., Laćan, M. & Meić, Z. (1975). Reaction of Aryldiazonium Chlorides with 1,3,5-Triketones. An Evidence for the Azohydrazone Conversion. Croatica Chemica Acta, 47 (2), 135-143. Retrieved from https://hrcak.srce.hr/196672
MLA 8th Edition
Škare, D., et al. "Reaction of Aryldiazonium Chlorides with 1,3,5-Triketones. An Evidence for the Azohydrazone Conversion." Croatica Chemica Acta, vol. 47, no. 2, 1975, pp. 135-143. https://hrcak.srce.hr/196672. Accessed 21 Apr. 2021.
Chicago 17th Edition
Škare, D., M. Laćan and Z. Meić. "Reaction of Aryldiazonium Chlorides with 1,3,5-Triketones. An Evidence for the Azohydrazone Conversion." Croatica Chemica Acta 47, no. 2 (1975): 135-143. https://hrcak.srce.hr/196672
Harvard
Škare, D., Laćan, M., and Meić, Z. (1975). 'Reaction of Aryldiazonium Chlorides with 1,3,5-Triketones. An Evidence for the Azohydrazone Conversion', Croatica Chemica Acta, 47(2), pp. 135-143. Available at: https://hrcak.srce.hr/196672 (Accessed 21 April 2021)
Vancouver
Škare D, Laćan M, Meić Z. Reaction of Aryldiazonium Chlorides with 1,3,5-Triketones. An Evidence for the Azohydrazone Conversion. Croatica Chemica Acta [Internet]. 1975 [cited 2021 April 21];47(2):135-143. Available from: https://hrcak.srce.hr/196672
IEEE
D. Škare, M. Laćan and Z. Meić, "Reaction of Aryldiazonium Chlorides with 1,3,5-Triketones. An Evidence for the Azohydrazone Conversion", Croatica Chemica Acta, vol.47, no. 2, pp. 135-143, 1975. [Online]. Available: https://hrcak.srce.hr/196672. [Accessed: 21 April 2021]

Abstracts
The coupling reactions of diazonium chlorides with sym-
1,3,5-triketones are described. The azo-form of the products · is
rearranged .into .the hydrazo-form during this reaction. Dihydrazones
(I) were formed in the sodiumacetate buffered so1ution
while in the sodium hydroxide solution both (I) and monohydrazones
(II) were formed. The spectroscopic analysis, based on the
data from infrared and ultraviolet spectra, indicates that dihydrazones
exist in the double syn-form with an intramolecular hydrogen
bond.

Hrčak ID: 196672

URI
https://hrcak.srce.hr/196672

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