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Hybridization in Highly Strained Small Ring Hydrocarbons. I. Tricyclo- and Tetracyclopropylidene

M. Randić ; Institute »Ruaer Boskovic«, Zagreb, Croatia, Yugoslavia
L. Jakab ; Institute »Ruaer Boskovic«, Zagreb, Croatia, Yugoslavia

Puni tekst: engleski, pdf (9 MB) str. 425-432 preuzimanja: 64* citiraj
APA 6th Edition
Randić, M. i Jakab, L. (1970). Hybridization in Highly Strained Small Ring Hydrocarbons. I. Tricyclo- and Tetracyclopropylidene. Croatica Chemica Acta, 42 (3), 425-432. Preuzeto s https://hrcak.srce.hr/197532
MLA 8th Edition
Randić, M. i L. Jakab. "Hybridization in Highly Strained Small Ring Hydrocarbons. I. Tricyclo- and Tetracyclopropylidene." Croatica Chemica Acta, vol. 42, br. 3, 1970, str. 425-432. https://hrcak.srce.hr/197532. Citirano 07.04.2020.
Chicago 17th Edition
Randić, M. i L. Jakab. "Hybridization in Highly Strained Small Ring Hydrocarbons. I. Tricyclo- and Tetracyclopropylidene." Croatica Chemica Acta 42, br. 3 (1970): 425-432. https://hrcak.srce.hr/197532
Harvard
Randić, M., i Jakab, L. (1970). 'Hybridization in Highly Strained Small Ring Hydrocarbons. I. Tricyclo- and Tetracyclopropylidene', Croatica Chemica Acta, 42(3), str. 425-432. Preuzeto s: https://hrcak.srce.hr/197532 (Datum pristupa: 07.04.2020.)
Vancouver
Randić M, Jakab L. Hybridization in Highly Strained Small Ring Hydrocarbons. I. Tricyclo- and Tetracyclopropylidene. Croatica Chemica Acta [Internet]. 1970 [pristupljeno 07.04.2020.];42(3):425-432. Dostupno na: https://hrcak.srce.hr/197532
IEEE
M. Randić i L. Jakab, "Hybridization in Highly Strained Small Ring Hydrocarbons. I. Tricyclo- and Tetracyclopropylidene", Croatica Chemica Acta, vol.42, br. 3, str. 425-432, 1970. [Online]. Dostupno na: https://hrcak.srce.hr/197532. [Citirano: 07.04.2020.]

Sažetak
The hybridization in tricyclopropylidene and tetracyclopropylidene
has been calculated by the method of maximum overlap.
The results show that the hybrids describing the central ring have
more s character than those in cyclopropane and cyclobutane:
sp3·02 and sp3·31 as compared to sp3·86 and sp3·47 respectively. Consequently the central bonds in the two molecules investigated . are
stabilized by the cyclopropyl substitutions. An interesting comparison
between the maximum overlap hybridization and hybridization
based on more elaborated calculations is made.

Hrčak ID: 197532

URI
https://hrcak.srce.hr/197532

Posjeta: 94 *