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The Thermodynamics of Formation of Metal Complexes and Ion-Pairs in Solution

G. H. Nancollas ; Chemistry Department, State University of New York at Buffalo, Buffalo, New York, U.S.A.

Puni tekst: engleski, pdf (13 MB) str. 299-310 preuzimanja: 1.308* citiraj
APA 6th Edition
Nancollas, G.H. (1970). The Thermodynamics of Formation of Metal Complexes and Ion-Pairs in Solution. Croatica Chemica Acta, 42 (2), 299-310. Preuzeto s https://hrcak.srce.hr/197554
MLA 8th Edition
Nancollas, G. H.. "The Thermodynamics of Formation of Metal Complexes and Ion-Pairs in Solution." Croatica Chemica Acta, vol. 42, br. 2, 1970, str. 299-310. https://hrcak.srce.hr/197554. Citirano 26.02.2021.
Chicago 17th Edition
Nancollas, G. H.. "The Thermodynamics of Formation of Metal Complexes and Ion-Pairs in Solution." Croatica Chemica Acta 42, br. 2 (1970): 299-310. https://hrcak.srce.hr/197554
Harvard
Nancollas, G.H. (1970). 'The Thermodynamics of Formation of Metal Complexes and Ion-Pairs in Solution', Croatica Chemica Acta, 42(2), str. 299-310. Preuzeto s: https://hrcak.srce.hr/197554 (Datum pristupa: 26.02.2021.)
Vancouver
Nancollas GH. The Thermodynamics of Formation of Metal Complexes and Ion-Pairs in Solution. Croatica Chemica Acta [Internet]. 1970 [pristupljeno 26.02.2021.];42(2):299-310. Dostupno na: https://hrcak.srce.hr/197554
IEEE
G.H. Nancollas, "The Thermodynamics of Formation of Metal Complexes and Ion-Pairs in Solution", Croatica Chemica Acta, vol.42, br. 2, str. 299-310, 1970. [Online]. Dostupno na: https://hrcak.srce.hr/197554. [Citirano: 26.02.2021.]

Sažetak
The problem of characterisation of species present at equilibrium
in an electrolyte solution is discussed. Shortcomings of the
free energy approach are shown due to inadmissible neglect of
entropy changes in complex formation. It is shown that complexes
formed with hard ligands are stabilised entirely by entropy
changes. Soft or covalent interactions are always characterized by
exothermic enthalpy changes.

Hrčak ID: 197554

URI
https://hrcak.srce.hr/197554

Posjeta: 1.358 *