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https://doi.org/10.5562/cca3362

Order-Disorder in Diaquobis(salicylato)copper(II) Revisited

Martin Lutz ; Crystal and Structural Chemistry, Bijvoet Center for Biomolecular Research, Utrecht University, Padualaan 8, 3584 CH Utrecht, The Netherlands
Loes M. J. Kroon-Batenburg   ORCID icon orcid.org/0000-0002-5321-1392 ; Crystal and Structural Chemistry, Bijvoet Center for Biomolecular Research, Utrecht University, Padualaan 8, 3584 CH Utrecht, The Netherlands

Puni tekst: engleski, pdf (11 MB) str. 289-298 preuzimanja: 297* citiraj
APA 6th Edition
Lutz, M. i Kroon-Batenburg, L.M.J. (2018). Order-Disorder in Diaquobis(salicylato)copper(II) Revisited. Croatica Chemica Acta, 91 (2), 289-298. https://doi.org/10.5562/cca3362
MLA 8th Edition
Lutz, Martin i Loes M. J. Kroon-Batenburg. "Order-Disorder in Diaquobis(salicylato)copper(II) Revisited." Croatica Chemica Acta, vol. 91, br. 2, 2018, str. 289-298. https://doi.org/10.5562/cca3362. Citirano 04.03.2021.
Chicago 17th Edition
Lutz, Martin i Loes M. J. Kroon-Batenburg. "Order-Disorder in Diaquobis(salicylato)copper(II) Revisited." Croatica Chemica Acta 91, br. 2 (2018): 289-298. https://doi.org/10.5562/cca3362
Harvard
Lutz, M., i Kroon-Batenburg, L.M.J. (2018). 'Order-Disorder in Diaquobis(salicylato)copper(II) Revisited', Croatica Chemica Acta, 91(2), str. 289-298. https://doi.org/10.5562/cca3362
Vancouver
Lutz M, Kroon-Batenburg LMJ. Order-Disorder in Diaquobis(salicylato)copper(II) Revisited. Croatica Chemica Acta [Internet]. 2018 [pristupljeno 04.03.2021.];91(2):289-298. https://doi.org/10.5562/cca3362
IEEE
M. Lutz i L.M.J. Kroon-Batenburg, "Order-Disorder in Diaquobis(salicylato)copper(II) Revisited", Croatica Chemica Acta, vol.91, br. 2, str. 289-298, 2018. [Online]. https://doi.org/10.5562/cca3362

Sažetak
We re-investigated the crystal structure of diaquobis(salicylato)copper(II), CuSal, which is an OD material with disordered layer stacking. The diffraction pattern consists of sharp Bragg spots and diffuse streaks.
From the Bragg reflections we determined the ordered part of the structure, which can either be described by an orthorhombic or a twinned monoclinic lattice. The main motif of the structure consists of one-dimensional coordination polymers that are connected by hydrogen bonds into two-dimensional layers.
The layer stacking is disordered and from simulations with a Markovian growth models we could fully explain the diffuse streaks of the current structure when the layers are stacked randomly.

Creative Commons License This work is licensed under a Creative Commons Attribution 4.0 International License.

Ključne riječi
diffuse scattering; OD structure; hydrogen-bonded layers; copper complex

Hrčak ID: 203021

URI
https://hrcak.srce.hr/203021

Posjeta: 394 *