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Kinetic Studies of the Formation of Iron (III) Ethylenediaminetetraacetate-Hydrogen Peroxide Complex

M . Orhanović ; Department of Chemistry, State University of New York at Buffalo, N. Y . 14214, U.S. A.
R. G. Wilkins ; Department of Chemistry, State University of New York at Buffalo, N. Y . 14214, U.S. A.

Puni tekst: engleski, pdf (6 MB) str. 149-154 preuzimanja: 43* citiraj
APA 6th Edition
Orhanović, M. i Wilkins, R.G. (1967). Kinetic Studies of the Formation of Iron (III) Ethylenediaminetetraacetate-Hydrogen Peroxide Complex. Croatica Chemica Acta, 39 (3), 149-154. Preuzeto s https://hrcak.srce.hr/208080
MLA 8th Edition
Orhanović, M . i R. G. Wilkins. "Kinetic Studies of the Formation of Iron (III) Ethylenediaminetetraacetate-Hydrogen Peroxide Complex." Croatica Chemica Acta, vol. 39, br. 3, 1967, str. 149-154. https://hrcak.srce.hr/208080. Citirano 06.04.2020.
Chicago 17th Edition
Orhanović, M . i R. G. Wilkins. "Kinetic Studies of the Formation of Iron (III) Ethylenediaminetetraacetate-Hydrogen Peroxide Complex." Croatica Chemica Acta 39, br. 3 (1967): 149-154. https://hrcak.srce.hr/208080
Harvard
Orhanović, M., i Wilkins, R.G. (1967). 'Kinetic Studies of the Formation of Iron (III) Ethylenediaminetetraacetate-Hydrogen Peroxide Complex', Croatica Chemica Acta, 39(3), str. 149-154. Preuzeto s: https://hrcak.srce.hr/208080 (Datum pristupa: 06.04.2020.)
Vancouver
Orhanović M, Wilkins RG. Kinetic Studies of the Formation of Iron (III) Ethylenediaminetetraacetate-Hydrogen Peroxide Complex. Croatica Chemica Acta [Internet]. 1967 [pristupljeno 06.04.2020.];39(3):149-154. Dostupno na: https://hrcak.srce.hr/208080
IEEE
M. Orhanović i R.G. Wilkins, "Kinetic Studies of the Formation of Iron (III) Ethylenediaminetetraacetate-Hydrogen Peroxide Complex", Croatica Chemica Acta, vol.39, br. 3, str. 149-154, 1967. [Online]. Dostupno na: https://hrcak.srce.hr/208080. [Citirano: 06.04.2020.]

Sažetak
The formation of· a red-purple iron (III) ethylenediaminetetraacetate
mono hydrogen peroxide species obeys the kinetic express ion
rate= k LFe(EDTA) (OH)2 3-J [H 202] over the range pH 9.0-11.0.
The Arrhenius equation, k = 1.9 X 10 7 exp (-6,700/RT) holds and
at 25°, k = 2.5 X 10 2 M - 1 sec-1• An enhanced rate above pH = 11 .0
may be associated with enhanced reactivity of [Fe(EDTA) (0H)3] 4-
or H02-. A brief compar ison is made of the results with data for
pe roxidase and catalase reactions with hydrogen peroxide.

Hrčak ID: 208080

URI
https://hrcak.srce.hr/208080

Posjeta: 68 *