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Precipitation and Hydrolysis of Thorium(IV) in Aqueous Solution. III. The Composition of the Precipitates in the System Thorium Nitrate - Potassium Phthalate

H. Bilinski ; Department of Physical Chemistry, Institute »Ruder Boskovic«, Zagreb, Croatia, Yugoslavia

Puni tekst: engleski, pdf (10 MB) str. 71-81 preuzimanja: 94* citiraj
APA 6th Edition
Bilinski, H. (1966). Precipitation and Hydrolysis of Thorium(IV) in Aqueous Solution. III. The Composition of the Precipitates in the System Thorium Nitrate - Potassium Phthalate. Croatica Chemica Acta, 38 (2), 71-81. Preuzeto s https://hrcak.srce.hr/208167
MLA 8th Edition
Bilinski, H.. "Precipitation and Hydrolysis of Thorium(IV) in Aqueous Solution. III. The Composition of the Precipitates in the System Thorium Nitrate - Potassium Phthalate." Croatica Chemica Acta, vol. 38, br. 2, 1966, str. 71-81. https://hrcak.srce.hr/208167. Citirano 09.03.2021.
Chicago 17th Edition
Bilinski, H.. "Precipitation and Hydrolysis of Thorium(IV) in Aqueous Solution. III. The Composition of the Precipitates in the System Thorium Nitrate - Potassium Phthalate." Croatica Chemica Acta 38, br. 2 (1966): 71-81. https://hrcak.srce.hr/208167
Harvard
Bilinski, H. (1966). 'Precipitation and Hydrolysis of Thorium(IV) in Aqueous Solution. III. The Composition of the Precipitates in the System Thorium Nitrate - Potassium Phthalate', Croatica Chemica Acta, 38(2), str. 71-81. Preuzeto s: https://hrcak.srce.hr/208167 (Datum pristupa: 09.03.2021.)
Vancouver
Bilinski H. Precipitation and Hydrolysis of Thorium(IV) in Aqueous Solution. III. The Composition of the Precipitates in the System Thorium Nitrate - Potassium Phthalate. Croatica Chemica Acta [Internet]. 1966 [pristupljeno 09.03.2021.];38(2):71-81. Dostupno na: https://hrcak.srce.hr/208167
IEEE
H. Bilinski, "Precipitation and Hydrolysis of Thorium(IV) in Aqueous Solution. III. The Composition of the Precipitates in the System Thorium Nitrate - Potassium Phthalate", Croatica Chemica Acta, vol.38, br. 2, str. 71-81, 1966. [Online]. Dostupno na: https://hrcak.srce.hr/208167. [Citirano: 09.03.2021.]

Sažetak
Precipitation from water solutions of thorium nitrate and
potassium phthalate was investigated for a broad range of concentrations
of both precipitation components. The influence of pH
and of time on the formation of various precipitates was studied,
the composition and characteristics of the precipitates being
determined by chemical analysis, and IR and NMR spectra. The
following precipitates were characterized:
Th(OH).:1 without water of crystallization;
Th (Phthalateh without water of crystallization;
Thorium hydroxide-phthalate polymer with unknown formula.
An empirical formula was derived, which shows the conditions
for precipitation of thorium hydroxide in the presence of potassium
phthalate. In the soluble mixed hydroxo-phthalato thorium
complex, two OH- ions are bound per one thorium.

Hrčak ID: 208167

URI
https://hrcak.srce.hr/208167

Posjeta: 134 *