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Izvorni znanstveni članak
Hybridization in Several Polycyclic Alkanes by the Method of Maximum Overlap
M. Randić
; Institute »Ruder Boskovic«, Zagreb, Croatia, Yugoslavia
J. M. Jerkunica
; Institute »Ruder Boskovic«, Zagreb, Croatia, Yugoslavia
D. Stefanović
; Institute »Ruder Boskovic«, Zagreb, Croatia, Yugoslavia
| Puni tekst: engleski, pdf (6 MB) | str. 49-54 | citiraj | |
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APA 6th Edition Randić, M., Jerkunica, J.M. i Stefanović, D. (1966). Hybridization in Several Polycyclic Alkanes by the Method of Maximum Overlap. Croatica Chemica Acta, 38 (1), 49-54. Preuzeto s https://hrcak.srce.hr/208183 MLA 8th Edition Randić, M., et al. "Hybridization in Several Polycyclic Alkanes by the Method of Maximum Overlap." Croatica Chemica Acta, vol. 38, br. 1, 1966, str. 49-54. https://hrcak.srce.hr/208183. Citirano 06.03.2021. Chicago 17th Edition Randić, M., J. M. Jerkunica i D. Stefanović. "Hybridization in Several Polycyclic Alkanes by the Method of Maximum Overlap." Croatica Chemica Acta 38, br. 1 (1966): 49-54. https://hrcak.srce.hr/208183 Harvard Randić, M., Jerkunica, J.M., i Stefanović, D. (1966). 'Hybridization in Several Polycyclic Alkanes by the Method of Maximum Overlap', Croatica Chemica Acta, 38(1), str. 49-54. Preuzeto s: https://hrcak.srce.hr/208183 (Datum pristupa: 06.03.2021.) Vancouver Randić M, Jerkunica JM, Stefanović D. Hybridization in Several Polycyclic Alkanes by the Method of Maximum Overlap. Croatica Chemica Acta [Internet]. 1966 [pristupljeno 06.03.2021.];38(1):49-54. Dostupno na: https://hrcak.srce.hr/208183 IEEE M. Randić, J.M. Jerkunica i D. Stefanović, "Hybridization in Several Polycyclic Alkanes by the Method of Maximum Overlap", Croatica Chemica Acta, vol.38, br. 1, str. 49-54, 1966. [Online]. Dostupno na: https://hrcak.srce.hr/208183. [Citirano: 06.03.2021.] |
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Sažetak
The hybridization · in spiropentane, nortricyclene, cu bane, tricyclo(
l.1.0.02,4)butane, bicyclo(l.1.l)pentane, and tetracyclo(3,3.l 2, 8.04,6)
nonane has been determined by the method of maximum
overlap. For the atomic functions Clementi Orbitals (ref. 1) have
been assumed. A comparison between these results and those,
obtained previously, by assuming Slater orbitals indicates the improvements that can be achieved by using more exact wave functions. The overlaps for CC bonds fall into the groups: (1) S < 0.61, (2) 0.61 < S < 0.63 and (3) S > 0.64. They are characteristic of highly
strained three-membered rings, (6 ~ 20°), of four membered rings,
(b ~ 10°), and of normal or very slightly bent bonds, (6 < 5°),
respectively.
Hrčak ID: 208183
URI
https://hrcak.srce.hr/208183
Moj profil
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